Spectroscopic studies of hydrogen formation from amineborane complexes

Nancy J. Hess, Craig M. Brown, Luke L. Daemen, Eugene Mamontov, R. Scott Smith, Bruce D. Kay, Wendy J. Shaw, John Linehan, Benjamin A. Schmid, Ashley C. Stowe, Maciej Gutowski, Tom Autrey

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Abstract

Spectroscopic methods are developed to investigate the chemical and physical properties of amine borane complexes. These materials are rich in hydrogen and are attractive candidates for hydrogen storage materials. Recent experimental results aimed at elucidation of the mechanism of hydrogen formation arising from ammonia borane (AB) confined within a mesoporous silica scaffold are presented. The approach, using solid state NMR, neutron scattering, and Raman spectroscopy is designed to gain a understanding of the nano-scale interfacial interactions that enhance the kinetics and thermodynamics of this hydrogen storage material. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

Original languageEnglish
Title of host publicationACS National Meeting Book of Abstracts
Volume230
Publication statusPublished - 2005
Event230th ACS National Meeting - Washington, DC, United States
Duration: Aug 28 2005Sep 1 2005

Other

Other230th ACS National Meeting
CountryUnited States
CityWashington, DC
Period8/28/059/1/05

Fingerprint

Boranes
Hydrogen
Hydrogen storage
Neutron scattering
Ammonia
Scaffolds
Silicon Dioxide
Chemical properties
Amines
Raman spectroscopy
Physical properties
Nuclear magnetic resonance
Thermodynamics
Kinetics

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Hess, N. J., Brown, C. M., Daemen, L. L., Mamontov, E., Smith, R. S., Kay, B. D., ... Autrey, T. (2005). Spectroscopic studies of hydrogen formation from amineborane complexes. In ACS National Meeting Book of Abstracts (Vol. 230)

Spectroscopic studies of hydrogen formation from amineborane complexes. / Hess, Nancy J.; Brown, Craig M.; Daemen, Luke L.; Mamontov, Eugene; Smith, R. Scott; Kay, Bruce D.; Shaw, Wendy J.; Linehan, John; Schmid, Benjamin A.; Stowe, Ashley C.; Gutowski, Maciej; Autrey, Tom.

ACS National Meeting Book of Abstracts. Vol. 230 2005.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

Hess, NJ, Brown, CM, Daemen, LL, Mamontov, E, Smith, RS, Kay, BD, Shaw, WJ, Linehan, J, Schmid, BA, Stowe, AC, Gutowski, M & Autrey, T 2005, Spectroscopic studies of hydrogen formation from amineborane complexes. in ACS National Meeting Book of Abstracts. vol. 230, 230th ACS National Meeting, Washington, DC, United States, 8/28/05.
Hess NJ, Brown CM, Daemen LL, Mamontov E, Smith RS, Kay BD et al. Spectroscopic studies of hydrogen formation from amineborane complexes. In ACS National Meeting Book of Abstracts. Vol. 230. 2005
Hess, Nancy J. ; Brown, Craig M. ; Daemen, Luke L. ; Mamontov, Eugene ; Smith, R. Scott ; Kay, Bruce D. ; Shaw, Wendy J. ; Linehan, John ; Schmid, Benjamin A. ; Stowe, Ashley C. ; Gutowski, Maciej ; Autrey, Tom. / Spectroscopic studies of hydrogen formation from amineborane complexes. ACS National Meeting Book of Abstracts. Vol. 230 2005.
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AU - Brown, Craig M.

AU - Daemen, Luke L.

AU - Mamontov, Eugene

AU - Smith, R. Scott

AU - Kay, Bruce D.

AU - Shaw, Wendy J.

AU - Linehan, John

AU - Schmid, Benjamin A.

AU - Stowe, Ashley C.

AU - Gutowski, Maciej

AU - Autrey, Tom

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AB - Spectroscopic methods are developed to investigate the chemical and physical properties of amine borane complexes. These materials are rich in hydrogen and are attractive candidates for hydrogen storage materials. Recent experimental results aimed at elucidation of the mechanism of hydrogen formation arising from ammonia borane (AB) confined within a mesoporous silica scaffold are presented. The approach, using solid state NMR, neutron scattering, and Raman spectroscopy is designed to gain a understanding of the nano-scale interfacial interactions that enhance the kinetics and thermodynamics of this hydrogen storage material. This is an abstract of a paper presented at the 230th ACS National Meeting (Washington, DC 8/28/2005-9/1/2005).

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