Abstract
In a three-site representation, we study a spin polarization transfer from radical pair spins to a nearby electron or nuclear spin. The quantum dynamics of the radical pair spins is governed by a constant exchange interaction between the radical pair spins which have different Zeeman frequencies. Radical pair spins can recombine to the singlet ground state or to lower energy triplet states. It is then shown that the coherent dynamics of the radical pair induces spin polarization on the nearby third spin in the presence of a magnetic field. The spin polarization transfer depends on the difference between Zeeman frequencies, the singlet and triplet recombination rates, and on the exchange and dipole-dipole interactions between the different spins. In particular, the sign of the polarization depends on the exchange coupling between radical pair spins and also on the difference between singlet and triplet recombination rate constants.
| Original language | English |
|---|---|
| Article number | 054101 |
| Journal | Journal of Chemical Physics |
| Volume | 143 |
| Issue number | 5 |
| DOIs | |
| Publication status | Published - Aug 7 2015 |
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ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry
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Spin polarization transfer by the radical pair mechanism. / Zarea, Mehdi; Ratner, Mark A; Wasielewski, Michael R.
In: Journal of Chemical Physics, Vol. 143, No. 5, 054101, 07.08.2015.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Spin polarization transfer by the radical pair mechanism
AU - Zarea, Mehdi
AU - Ratner, Mark A
AU - Wasielewski, Michael R
PY - 2015/8/7
Y1 - 2015/8/7
N2 - In a three-site representation, we study a spin polarization transfer from radical pair spins to a nearby electron or nuclear spin. The quantum dynamics of the radical pair spins is governed by a constant exchange interaction between the radical pair spins which have different Zeeman frequencies. Radical pair spins can recombine to the singlet ground state or to lower energy triplet states. It is then shown that the coherent dynamics of the radical pair induces spin polarization on the nearby third spin in the presence of a magnetic field. The spin polarization transfer depends on the difference between Zeeman frequencies, the singlet and triplet recombination rates, and on the exchange and dipole-dipole interactions between the different spins. In particular, the sign of the polarization depends on the exchange coupling between radical pair spins and also on the difference between singlet and triplet recombination rate constants.
AB - In a three-site representation, we study a spin polarization transfer from radical pair spins to a nearby electron or nuclear spin. The quantum dynamics of the radical pair spins is governed by a constant exchange interaction between the radical pair spins which have different Zeeman frequencies. Radical pair spins can recombine to the singlet ground state or to lower energy triplet states. It is then shown that the coherent dynamics of the radical pair induces spin polarization on the nearby third spin in the presence of a magnetic field. The spin polarization transfer depends on the difference between Zeeman frequencies, the singlet and triplet recombination rates, and on the exchange and dipole-dipole interactions between the different spins. In particular, the sign of the polarization depends on the exchange coupling between radical pair spins and also on the difference between singlet and triplet recombination rate constants.
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UR - http://www.scopus.com/inward/citedby.url?scp=84938631344&partnerID=8YFLogxK
U2 - 10.1063/1.4927589
DO - 10.1063/1.4927589
M3 - Article
AN - SCOPUS:84938631344
VL - 143
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 5
M1 - 054101
ER -