Abstract
In the past few years, spiropyran has emerged as the molecule-of-choice for the construction of novel dynamic materials. This unique molecular switch undergoes structural isomerisation in response to a variety of orthogonal stimuli, e.g. light, temperature, metal ions, redox potential, and mechanical stress. Incorporation of this switch onto macromolecular supports or inorganic scaffolds allows for the creation of robust dynamic materials. This review discusses the synthesis, switching conditions, and use of dynamic materials in which spiropyran has been attached to the surfaces of polymers, biomacromolecules, inorganic nanoparticles, as well as solid surfaces. The resulting materials show fascinating properties whereby the state of the switch intimately affects a multitude of useful properties of the support. The utility of the spiropyran switch will undoubtedly endow these materials with far-reaching applications in the near future.
| Original language | English |
|---|---|
| Pages (from-to) | 148-184 |
| Number of pages | 37 |
| Journal | Chemical Society Reviews |
| Volume | 43 |
| Issue number | 1 |
| DOIs | |
| Publication status | Published - Jan 7 2014 |
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ASJC Scopus subject areas
- Chemistry(all)
Cite this
Spiropyran-based dynamic materials. / Klajn, Rafal.
In: Chemical Society Reviews, Vol. 43, No. 1, 07.01.2014, p. 148-184.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Spiropyran-based dynamic materials
AU - Klajn, Rafal
PY - 2014/1/7
Y1 - 2014/1/7
N2 - In the past few years, spiropyran has emerged as the molecule-of-choice for the construction of novel dynamic materials. This unique molecular switch undergoes structural isomerisation in response to a variety of orthogonal stimuli, e.g. light, temperature, metal ions, redox potential, and mechanical stress. Incorporation of this switch onto macromolecular supports or inorganic scaffolds allows for the creation of robust dynamic materials. This review discusses the synthesis, switching conditions, and use of dynamic materials in which spiropyran has been attached to the surfaces of polymers, biomacromolecules, inorganic nanoparticles, as well as solid surfaces. The resulting materials show fascinating properties whereby the state of the switch intimately affects a multitude of useful properties of the support. The utility of the spiropyran switch will undoubtedly endow these materials with far-reaching applications in the near future.
AB - In the past few years, spiropyran has emerged as the molecule-of-choice for the construction of novel dynamic materials. This unique molecular switch undergoes structural isomerisation in response to a variety of orthogonal stimuli, e.g. light, temperature, metal ions, redox potential, and mechanical stress. Incorporation of this switch onto macromolecular supports or inorganic scaffolds allows for the creation of robust dynamic materials. This review discusses the synthesis, switching conditions, and use of dynamic materials in which spiropyran has been attached to the surfaces of polymers, biomacromolecules, inorganic nanoparticles, as well as solid surfaces. The resulting materials show fascinating properties whereby the state of the switch intimately affects a multitude of useful properties of the support. The utility of the spiropyran switch will undoubtedly endow these materials with far-reaching applications in the near future.
UR - http://www.scopus.com/inward/record.url?scp=84889029977&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84889029977&partnerID=8YFLogxK
U2 - 10.1039/c3cs60181a
DO - 10.1039/c3cs60181a
M3 - Article
C2 - 23979515
AN - SCOPUS:84889029977
VL - 43
SP - 148
EP - 184
JO - Chemical Society Reviews
JF - Chemical Society Reviews
SN - 0306-0012
IS - 1
ER -