Abstract
In transition metal compounds of edge-sharing square planarMX4units (M=group 10, group 11;X=O, S, Se), a square planar to rectangular distortion is observed. The causes for this distortion inMX2ladder chains,M3X4honeycomb layers, and 3DMXlattices were examined by performing extended Hückel tight binding electronic band structure calculations. The primary cause for the distortion is the reduction of the four-electron two-orbital destabilizing interactions among thep-orbitals ofX.
| Original language | English |
|---|---|
| Pages (from-to) | 181-184 |
| Number of pages | 4 |
| Journal | Journal of Solid State Chemistry |
| Volume | 128 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Feb 1 1997 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Square Planar to Rectangular Distortion in Transition-Metal Compounds of Edge-Sharing Square Planar UnitsMX4. / Gupta, N.; Seo, Dong Kyun; Whangbo, M. H.; Jobic, S.; Rouxel, J.; Brec, R.
In: Journal of Solid State Chemistry, Vol. 128, No. 2, 01.02.1997, p. 181-184.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Square Planar to Rectangular Distortion in Transition-Metal Compounds of Edge-Sharing Square Planar UnitsMX4
AU - Gupta, N.
AU - Seo, Dong Kyun
AU - Whangbo, M. H.
AU - Jobic, S.
AU - Rouxel, J.
AU - Brec, R.
PY - 1997/2/1
Y1 - 1997/2/1
N2 - In transition metal compounds of edge-sharing square planarMX4units (M=group 10, group 11;X=O, S, Se), a square planar to rectangular distortion is observed. The causes for this distortion inMX2ladder chains,M3X4honeycomb layers, and 3DMXlattices were examined by performing extended Hückel tight binding electronic band structure calculations. The primary cause for the distortion is the reduction of the four-electron two-orbital destabilizing interactions among thep-orbitals ofX.
AB - In transition metal compounds of edge-sharing square planarMX4units (M=group 10, group 11;X=O, S, Se), a square planar to rectangular distortion is observed. The causes for this distortion inMX2ladder chains,M3X4honeycomb layers, and 3DMXlattices were examined by performing extended Hückel tight binding electronic band structure calculations. The primary cause for the distortion is the reduction of the four-electron two-orbital destabilizing interactions among thep-orbitals ofX.
UR - http://www.scopus.com/inward/record.url?scp=0013487121&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0013487121&partnerID=8YFLogxK
U2 - 10.1006/jssc.1996.7177
DO - 10.1006/jssc.1996.7177
M3 - Article
VL - 128
SP - 181
EP - 184
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
SN - 0022-4596
IS - 2
ER -