Stability and hydrogen adsorption of metal-organic frameworks prepared via different catalyst doping methods

Cheng Yu Wang, Qihan Gong, Yonggang Zhao, Jing Li, Angela D. Lueking

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The stability of three metal-organic frameworks (MOFs), namely IRMOF-8, Cu-TDPAT, and Cu-BTC, was tested after incorporation of Pt. Stability was assessed with powder X-ray diffraction (PXRD), physical (N2 at 77 K) and chemical (H2 at 300 K) adsorption, and thermogravimetric analysis in H2 and N2. Introduction of Pt via wet precipitation led to MOF degradation during the H2 reduction step. Addition of pre-reduced Pt supported on activated carbon (Pt/AC) to MOFs via physical mixing also led to structural degradation. However, addition of Pt/AC via a 'pre-bridge' (PB) technique led to high MOF stability, with the retention of surface area, porosity, crystallinity, and thermal stability. The catalytically active surface area was assessed by hydrogen adsorption, and demonstrated extension of the catalytically active surface area to the MOF surface. High hydrogen uptake correlated with MOF particle size, due to the connectivity between Pt/AC and MOF, and the interpenetration of Pt/AC into the MOF crystal.

Original languageEnglish
Pages (from-to)128-142
Number of pages15
JournalJournal of Catalysis
Volume318
DOIs
Publication statusPublished - 2014

Fingerprint

Hydrogen
Metals
Doping (additives)
Adsorption
catalysts
Catalysts
adsorption
hydrogen
metals
alternating current
degradation
Degradation
activated carbon
Activated carbon
X ray powder diffraction
Thermogravimetric analysis
crystallinity
Thermodynamic stability
thermal stability
Porosity

Keywords

  • Catalytic doping
  • Hydrogen spillover
  • Metal organic frameworks
  • Pt nanoparticles

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry

Cite this

Stability and hydrogen adsorption of metal-organic frameworks prepared via different catalyst doping methods. / Wang, Cheng Yu; Gong, Qihan; Zhao, Yonggang; Li, Jing; Lueking, Angela D.

In: Journal of Catalysis, Vol. 318, 2014, p. 128-142.

Research output: Contribution to journalArticle

Wang, Cheng Yu ; Gong, Qihan ; Zhao, Yonggang ; Li, Jing ; Lueking, Angela D. / Stability and hydrogen adsorption of metal-organic frameworks prepared via different catalyst doping methods. In: Journal of Catalysis. 2014 ; Vol. 318. pp. 128-142.
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