Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J. Clingerman, William Morris, Joseph E. Mondloch, Robert D. Kennedy, Amy A. Sarjeant, Charlotte Stern, Joseph T. Hupp, Omar K. Farha, Chad A. Mirkin

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20 Citations (Scopus)

Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g-1. This journal is

Original languageEnglish
Pages (from-to)6521-6523
Number of pages3
JournalChemical Communications
Volume51
Issue number30
DOIs
Publication statusPublished - Apr 18 2015

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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    Clingerman, D. J., Morris, W., Mondloch, J. E., Kennedy, R. D., Sarjeant, A. A., Stern, C., Hupp, J. T., Farha, O. K., & Mirkin, C. A. (2015). Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. Chemical Communications, 51(30), 6521-6523. https://doi.org/10.1039/c4cc09212k