Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J. Clingerman, William Morris, Joseph E. Mondloch, Robert D. Kennedy, Amy A. Sarjeant, Charlotte Stern, Joseph T Hupp, Omar K. Farha, Chad A. Mirkin

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g-1. This journal is

Original languageEnglish
Pages (from-to)6521-6523
Number of pages3
JournalChemical Communications
Volume51
Issue number30
DOIs
Publication statusPublished - Apr 18 2015

Fingerprint

Stabilization
Metals
Porosity
4-(2,5,5-trimethyl-4-aza-2-mercaptohexyl)-6,6-dimethyl-2-thiomorpholinone

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Surfaces, Coatings and Films
  • Materials Chemistry
  • Metals and Alloys

Cite this

Clingerman, D. J., Morris, W., Mondloch, J. E., Kennedy, R. D., Sarjeant, A. A., Stern, C., ... Mirkin, C. A. (2015). Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. Chemical Communications, 51(30), 6521-6523. https://doi.org/10.1039/c4cc09212k

Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. / Clingerman, Daniel J.; Morris, William; Mondloch, Joseph E.; Kennedy, Robert D.; Sarjeant, Amy A.; Stern, Charlotte; Hupp, Joseph T; Farha, Omar K.; Mirkin, Chad A.

In: Chemical Communications, Vol. 51, No. 30, 18.04.2015, p. 6521-6523.

Research output: Contribution to journalArticle

Clingerman, DJ, Morris, W, Mondloch, JE, Kennedy, RD, Sarjeant, AA, Stern, C, Hupp, JT, Farha, OK & Mirkin, CA 2015, 'Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker', Chemical Communications, vol. 51, no. 30, pp. 6521-6523. https://doi.org/10.1039/c4cc09212k
Clingerman DJ, Morris W, Mondloch JE, Kennedy RD, Sarjeant AA, Stern C et al. Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. Chemical Communications. 2015 Apr 18;51(30):6521-6523. https://doi.org/10.1039/c4cc09212k
Clingerman, Daniel J. ; Morris, William ; Mondloch, Joseph E. ; Kennedy, Robert D. ; Sarjeant, Amy A. ; Stern, Charlotte ; Hupp, Joseph T ; Farha, Omar K. ; Mirkin, Chad A. / Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. In: Chemical Communications. 2015 ; Vol. 51, No. 30. pp. 6521-6523.
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