Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J. Clingerman; William Morris; Joseph E. Mondloch; Robert D. Kennedy; Amy A. Sarjeant; Charlotte Stern; Joseph T. Hupp; Omar K. Farha; Chad A. Mirkin

doi:10.1039/c4cc09212k

Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Daniel J. Clingerman, William Morris, Joseph E. Mondloch, Robert D. Kennedy, Amy A. Sarjeant, Charlotte Stern, Joseph T. Hupp, Omar K. Farha, Chad A. Mirkin

Northwestern University

Research output: Contribution to journal › Article › peer-review

25 Citations (Scopus)

Abstract

The first tritopic carborane-based linker, H₃BCA (C₁₅B₂₄O₆H₃₀), based on closo-1,10-C₂B₈H₁₀, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu₃(BCA)₂). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m² g^-1. This journal is

Original language	English
Pages (from-to)	6521-6523
Number of pages	3
Journal	Chemical Communications
Volume	51
Issue number	30
DOIs	https://doi.org/10.1039/c4cc09212k
Publication status	Published - Apr 18 2015

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker. / Clingerman, Daniel J.; Morris, William; Mondloch, Joseph E.; Kennedy, Robert D.; Sarjeant, Amy A.; Stern, Charlotte; Hupp, Joseph T.; Farha, Omar K.; Mirkin, Chad A.

In: Chemical Communications, Vol. 51, No. 30, 18.04.2015, p. 6521-6523.

Research output: Contribution to journal › Article › peer-review

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abstract = "The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal-organic framework (MOF), NU-700 (Cu3(BCA)2). In contrast to the analogous MOF-143, NU-700 can be activated with retention of porosity, yielding a BET surface area of 1870 m2 g-1. This journal is",

author = "Clingerman, {Daniel J.} and William Morris and Mondloch, {Joseph E.} and Kennedy, {Robert D.} and Sarjeant, {Amy A.} and Charlotte Stern and Hupp, {Joseph T.} and Farha, {Omar K.} and Mirkin, {Chad A.}",

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AU - Sarjeant, Amy A.

AU - Stern, Charlotte

AU - Hupp, Joseph T.

AU - Farha, Omar K.

AU - Mirkin, Chad A.

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Stabilization of a highly porous metal-organic framework utilizing a carborane-based linker

Abstract

ASJC Scopus subject areas

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