Abstract
An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.
Original language | English |
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Pages (from-to) | 171-173 |
Number of pages | 3 |
Journal | Chemical Physics Letters |
Volume | 89 |
Issue number | 2 |
DOIs | |
Publication status | Published - Jun 11 1982 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces