Abstract
An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.
| Original language | English |
|---|---|
| Pages (from-to) | 171-173 |
| Number of pages | 3 |
| Journal | Chemical Physics Letters |
| Volume | 89 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - Jun 11 1982 |
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ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Spectroscopy
- Condensed Matter Physics
- Atomic and Molecular Physics, and Optics
- Surfaces and Interfaces
Cite this
Statistical wavefunction method for highly excited vibrational states of polyatomic molecules. / Gerber, R. B.; Buch, Victoria; Ratner, Mark A.
In: Chemical Physics Letters, Vol. 89, No. 2, 11.06.1982, p. 171-173.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Statistical wavefunction method for highly excited vibrational states of polyatomic molecules
AU - Gerber, R. B.
AU - Buch, Victoria
AU - Ratner, Mark A
PY - 1982/6/11
Y1 - 1982/6/11
N2 - An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.
AB - An approximation is proposed for calculations of average properties of high-lying vibrational states of polyatomics. The method employs a statistical model for the wavefunctions. The approximation was tested against exact, extensive numerical results for transition moment distributions in two-mode model systems. Good agreement was found.
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UR - http://www.scopus.com/inward/citedby.url?scp=49049137054&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(82)83396-4
DO - 10.1016/0009-2614(82)83396-4
M3 - Article
AN - SCOPUS:49049137054
VL - 89
SP - 171
EP - 173
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 2
ER -