Stepwise assembly of coordination-based metal-organic networks

Revital Kaminker, Leila Motiei, Antonino Gulino, Ignazio Fragalà, Linda J W Shimon, Guennadi Evmenenko, Pulak Dutta, Mark A. Iron, Milko van der Boom

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl 2. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.

Original languageEnglish
Pages (from-to)14554-14561
Number of pages8
JournalJournal of the American Chemical Society
Volume132
Issue number41
DOIs
Publication statusPublished - Oct 20 2010

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Photoelectron Spectroscopy
X ray photoelectron spectroscopy
Metals
Synchrotrons
Atomic Force Microscopy
Ellipsometry
Palladium
Ultraviolet spectroscopy
Atomic force microscopy
Spectrum Analysis
X-Rays
X rays
Geometry
Chemical analysis

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Kaminker, R., Motiei, L., Gulino, A., Fragalà, I., Shimon, L. J. W., Evmenenko, G., ... van der Boom, M. (2010). Stepwise assembly of coordination-based metal-organic networks. Journal of the American Chemical Society, 132(41), 14554-14561. https://doi.org/10.1021/ja105518n

Stepwise assembly of coordination-based metal-organic networks. / Kaminker, Revital; Motiei, Leila; Gulino, Antonino; Fragalà, Ignazio; Shimon, Linda J W; Evmenenko, Guennadi; Dutta, Pulak; Iron, Mark A.; van der Boom, Milko.

In: Journal of the American Chemical Society, Vol. 132, No. 41, 20.10.2010, p. 14554-14561.

Research output: Contribution to journalArticle

Kaminker, R, Motiei, L, Gulino, A, Fragalà, I, Shimon, LJW, Evmenenko, G, Dutta, P, Iron, MA & van der Boom, M 2010, 'Stepwise assembly of coordination-based metal-organic networks', Journal of the American Chemical Society, vol. 132, no. 41, pp. 14554-14561. https://doi.org/10.1021/ja105518n
Kaminker R, Motiei L, Gulino A, Fragalà I, Shimon LJW, Evmenenko G et al. Stepwise assembly of coordination-based metal-organic networks. Journal of the American Chemical Society. 2010 Oct 20;132(41):14554-14561. https://doi.org/10.1021/ja105518n
Kaminker, Revital ; Motiei, Leila ; Gulino, Antonino ; Fragalà, Ignazio ; Shimon, Linda J W ; Evmenenko, Guennadi ; Dutta, Pulak ; Iron, Mark A. ; van der Boom, Milko. / Stepwise assembly of coordination-based metal-organic networks. In: Journal of the American Chemical Society. 2010 ; Vol. 132, No. 41. pp. 14554-14561.
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