Stereochemically nonrigid organometallic molecules. XX. Proton nuclear magnetic resonance study of the fluxional behavior of some substituted ( 1,2,7-trihaptobenzyl)-(pentahzoptocyclopentadienyl)dicarbonyl compounds of molybdenum and tungsten

F. A. Cotton, Tobin J Marks

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107 Citations (Scopus)

Abstract

Several new fluxional molecules containing substituted 1,2,7-trihaptobenzyl groups bound to the (C5H5)Mo(CO)2 and (C5H5)W(CO)2 residues have been prepared and their proton magnetic resonance spectra studied with the objective of elucidating the pathway and evaluating the activation parameters concerned in the flujfional behavior of this class of molecules. The molecules are less difficult to prepare and more stable than previously reported. The chief qualitative conclusion, derived from the study of the 3,5-diisopropylbenzyl compound, is that the (C5H5)Mo(CO)2 residue has access to all four equivalent (including enantiomorphically related) positions of attachment to the benzyl group. A plausible pathway would be via a monohapto- (i.e., σ-) C6H5CH2Mo(C5H5)(CO) 2 intermediate, in which rotation about the C1-C7 bond of the benzyl group can occur.

Original languageEnglish
Pages (from-to)1339-1346
Number of pages8
JournalJournal of the American Chemical Society
Volume91
Issue number6
Publication statusPublished - 1969

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Tungsten Compounds
Tungsten
Molybdenum
Organometallics
Protons
Magnetic Resonance Spectroscopy
Nuclear magnetic resonance
Molecules
Chemical activation

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Stereochemically nonrigid organometallic molecules. XX. Proton nuclear magnetic resonance study of the fluxional behavior of some substituted ( 1,2,7-trihaptobenzyl)-(pentahzoptocyclopentadienyl)dicarbonyl compounds of molybdenum and tungsten",
abstract = "Several new fluxional molecules containing substituted 1,2,7-trihaptobenzyl groups bound to the (C5H5)Mo(CO)2 and (C5H5)W(CO)2 residues have been prepared and their proton magnetic resonance spectra studied with the objective of elucidating the pathway and evaluating the activation parameters concerned in the flujfional behavior of this class of molecules. The molecules are less difficult to prepare and more stable than previously reported. The chief qualitative conclusion, derived from the study of the 3,5-diisopropylbenzyl compound, is that the (C5H5)Mo(CO)2 residue has access to all four equivalent (including enantiomorphically related) positions of attachment to the benzyl group. A plausible pathway would be via a monohapto- (i.e., σ-) C6H5CH2Mo(C5H5)(CO) 2 intermediate, in which rotation about the C1-C7 bond of the benzyl group can occur.",
author = "Cotton, {F. A.} and Marks, {Tobin J}",
year = "1969",
language = "English",
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pages = "1339--1346",
journal = "Journal of the American Chemical Society",
issn = "0002-7863",
publisher = "American Chemical Society",
number = "6",

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TY - JOUR

T1 - Stereochemically nonrigid organometallic molecules. XX. Proton nuclear magnetic resonance study of the fluxional behavior of some substituted ( 1,2,7-trihaptobenzyl)-(pentahzoptocyclopentadienyl)dicarbonyl compounds of molybdenum and tungsten

AU - Cotton, F. A.

AU - Marks, Tobin J

PY - 1969

Y1 - 1969

N2 - Several new fluxional molecules containing substituted 1,2,7-trihaptobenzyl groups bound to the (C5H5)Mo(CO)2 and (C5H5)W(CO)2 residues have been prepared and their proton magnetic resonance spectra studied with the objective of elucidating the pathway and evaluating the activation parameters concerned in the flujfional behavior of this class of molecules. The molecules are less difficult to prepare and more stable than previously reported. The chief qualitative conclusion, derived from the study of the 3,5-diisopropylbenzyl compound, is that the (C5H5)Mo(CO)2 residue has access to all four equivalent (including enantiomorphically related) positions of attachment to the benzyl group. A plausible pathway would be via a monohapto- (i.e., σ-) C6H5CH2Mo(C5H5)(CO) 2 intermediate, in which rotation about the C1-C7 bond of the benzyl group can occur.

AB - Several new fluxional molecules containing substituted 1,2,7-trihaptobenzyl groups bound to the (C5H5)Mo(CO)2 and (C5H5)W(CO)2 residues have been prepared and their proton magnetic resonance spectra studied with the objective of elucidating the pathway and evaluating the activation parameters concerned in the flujfional behavior of this class of molecules. The molecules are less difficult to prepare and more stable than previously reported. The chief qualitative conclusion, derived from the study of the 3,5-diisopropylbenzyl compound, is that the (C5H5)Mo(CO)2 residue has access to all four equivalent (including enantiomorphically related) positions of attachment to the benzyl group. A plausible pathway would be via a monohapto- (i.e., σ-) C6H5CH2Mo(C5H5)(CO) 2 intermediate, in which rotation about the C1-C7 bond of the benzyl group can occur.

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