Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

Michel R. Gagné, Laurent Brard, Vincent P. Conticello, Michael A. Giardello, Charlotte L. Stern, Tobin J Marks

Research output: Contribution to journal › Article

189 Citations (Scopus)

Abstract

The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

Original languageEnglish
Pages (from-to)2003-2005
Number of pages3
JournalOrganometallics
Volume11
Issue number6
Publication statusPublished - 1992

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Pyrrolidines
Piperidines
piperidine
Cyclization
methylidyne

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Gagné, M. R., Brard, L., Conticello, V. P., Giardello, M. A., Stern, C. L., & Marks, T. J. (1992). Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. Organometallics, 11(6), 2003-2005.

Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. / Gagné, Michel R.; Brard, Laurent; Conticello, Vincent P.; Giardello, Michael A.; Stern, Charlotte L.; Marks, Tobin J.

In: Organometallics, Vol. 11, No. 6, 1992, p. 2003-2005.

Research output: Contribution to journal › Article

Gagné, MR, Brard, L, Conticello, VP, Giardello, MA, Stern, CL & Marks, TJ 1992, 'Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers', Organometallics, vol. 11, no. 6, pp. 2003-2005.
Gagné MR, Brard L, Conticello VP, Giardello MA, Stern CL, Marks TJ. Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. Organometallics. 1992;11(6):2003-2005.
Gagné, Michel R. ; Brard, Laurent ; Conticello, Vincent P. ; Giardello, Michael A. ; Stern, Charlotte L. ; Marks, Tobin J. / Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. In: Organometallics. 1992 ; Vol. 11, No. 6. pp. 2003-2005.
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