Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

Michel R. Gagné; Laurent Brard; Vincent P. Conticello; Michael A. Giardello; Charlotte L. Stern; Tobin J Marks

Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

Michel R. Gagné, Laurent Brard, Vincent P. Conticello, Michael A. Giardello, Charlotte L. Stern, Tobin J Marks

Northwestern University

Research output: Contribution to journal › Article › peer-review

189 Citations (Scopus)

Abstract

The chiral organolanthanide complexes Me₂Si(Me₄C₅)(C₅H ₃R*)LnE(SiMe₃)₂ (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

Original language	English
Pages (from-to)	2003-2005
Number of pages	3
Journal	Organometallics
Volume	11
Issue number	6
Publication status	Published - 1992

ASJC Scopus subject areas

Inorganic Chemistry
Organic Chemistry

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@article{d1b51cd122cc47daa22bbf312f645aef,

title = "Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers",

abstract = "The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.",

author = "Gagn{\'e}, {Michel R.} and Laurent Brard and Conticello, {Vincent P.} and Giardello, {Michael A.} and Stern, {Charlotte L.} and Marks, {Tobin J}",

year = "1992",

language = "English",

volume = "11",

pages = "2003--2005",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

AU - Gagné, Michel R.

AU - Brard, Laurent

AU - Conticello, Vincent P.

AU - Giardello, Michael A.

AU - Stern, Charlotte L.

AU - Marks, Tobin J

PY - 1992

Y1 - 1992

N2 - The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

AB - The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

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UR - http://www.scopus.com/inward/citedby.url?scp=0001249546&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0001249546

VL - 11

SP - 2003

EP - 2005

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 6

ER -