Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

Michel R. Gagné, Laurent Brard, Vincent P. Conticello, Michael A. Giardello, Charlotte L. Stern, Tobin J Marks

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Abstract

The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

Original languageEnglish
Pages (from-to)2003-2005
Number of pages3
JournalOrganometallics
Volume11
Issue number6
Publication statusPublished - 1992

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ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Gagné, M. R., Brard, L., Conticello, V. P., Giardello, M. A., Stern, C. L., & Marks, T. J. (1992). Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. Organometallics, 11(6), 2003-2005.