Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

Michel R. Gagné, Laurent Brard, Vincent P. Conticello, Michael A. Giardello, Charlotte L. Stern, Tobin J Marks

Research output: Contribution to journalArticle

188 Citations (Scopus)

Abstract

The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

Original languageEnglish
Pages (from-to)2003-2005
Number of pages3
JournalOrganometallics
Volume11
Issue number6
Publication statusPublished - 1992

Fingerprint

Pyrrolidines
Piperidines
piperidine
Cyclization
methylidyne

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Gagné, M. R., Brard, L., Conticello, V. P., Giardello, M. A., Stern, C. L., & Marks, T. J. (1992). Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. Organometallics, 11(6), 2003-2005.

Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. / Gagné, Michel R.; Brard, Laurent; Conticello, Vincent P.; Giardello, Michael A.; Stern, Charlotte L.; Marks, Tobin J.

In: Organometallics, Vol. 11, No. 6, 1992, p. 2003-2005.

Research output: Contribution to journalArticle

Gagné, MR, Brard, L, Conticello, VP, Giardello, MA, Stern, CL & Marks, TJ 1992, 'Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers', Organometallics, vol. 11, no. 6, pp. 2003-2005.
Gagné, Michel R. ; Brard, Laurent ; Conticello, Vincent P. ; Giardello, Michael A. ; Stern, Charlotte L. ; Marks, Tobin J. / Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers. In: Organometallics. 1992 ; Vol. 11, No. 6. pp. 2003-2005.
@article{d1b51cd122cc47daa22bbf312f645aef,
title = "Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers",
abstract = "The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.",
author = "Gagn{\'e}, {Michel R.} and Laurent Brard and Conticello, {Vincent P.} and Giardello, {Michael A.} and Stern, {Charlotte L.} and Marks, {Tobin J}",
year = "1992",
language = "English",
volume = "11",
pages = "2003--2005",
journal = "Organometallics",
issn = "0276-7333",
publisher = "American Chemical Society",
number = "6",

}

TY - JOUR

T1 - Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers

AU - Gagné, Michel R.

AU - Brard, Laurent

AU - Conticello, Vincent P.

AU - Giardello, Michael A.

AU - Stern, Charlotte L.

AU - Marks, Tobin J

PY - 1992

Y1 - 1992

N2 - The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

AB - The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

UR - http://www.scopus.com/inward/record.url?scp=0001249546&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001249546&partnerID=8YFLogxK

M3 - Article

VL - 11

SP - 2003

EP - 2005

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 6

ER -