Abstract
The chiral organolanthanide complexes Me2Si(Me4C5)(C5H 3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantioselective or diastereoselective hydroamination/cyclization of aminoolefins to chiral pyrrolidines and piperidines.
Original language | English |
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Pages (from-to) | 2003-2005 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 11 |
Issue number | 6 |
Publication status | Published - 1992 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry