Strongly nonlinear optical chalcogenide thin films of APSe 6 (A=K, Rb) from spin-coating

In Chung, Myung Gil Kim, Joon I. Jang, Jiaqing He, John B. Ketterson, Mercouri G. Kanatzidis

Research output: Contribution to journalArticlepeer-review

35 Citations (Scopus)


The first example of solution-based deposition of strongly nonlinear optical inorganic thin films at low temperatures of 125-250 °C is presented. The obtained glassy and crystalline films of highly nonlinear APSe 6 compounds (A=K, Rb; π (2)≈150 pm V -1) exhibit strong, inherent second harmonic and difference frequency generation (SHG and DFG) in the visible and near-IR spectral region at room temperature without the need of poling (see picture).

Original languageEnglish
Pages (from-to)10867-10870
Number of pages4
JournalAngewandte Chemie - International Edition
Issue number46
Publication statusPublished - Nov 11 2011


  • nonlinear optics
  • phase transitions
  • selenophosphates
  • solution processes
  • thin films

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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