Abstract
Although some perovskite oxides have been shown to be stable solid oxide fuel cell (SOFC) anodes, the actual crystal structure of these materials under operating conditions is largely unknown. In this paper, the structural evolution of the SOFC anode La0.30Sr0.70Fe0.70Cr 0.30O3-δ was studied at 800 and 900 °C (similar to SOFC operating temperatures) in progressively reducing and oxidizing environments. The perovskite was shown to be stable down to a pO2 of 10-20 atm at 800 °C and a pO2 of 10-18 atm at 900 °C, at which point a spinel phase formed. Further reduction led to the formation of Fe metal. The phase separation of La0.30Sr 0.70Fe0.70Cr0.30O3-δ was also shown to be completely reversible with an increase in the partial oxygen pressure and reoxidation of the sample.
| Original language | English |
|---|---|
| Pages (from-to) | 3283-3289 |
| Number of pages | 7 |
| Journal | Chemistry of Materials |
| Volume | 22 |
| Issue number | 10 |
| DOIs | |
| Publication status | Published - May 25 2010 |
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ASJC Scopus subject areas
- Materials Chemistry
- Chemical Engineering(all)
- Chemistry(all)
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Structural and chemical evolution of the SOFC anode La 0.30Sr0.70Fe0.70Cr0.30O 3-δ upon reduction and oxidation : An in situ neutron diffraction study. / Haag, Jacob M.; Barnett, Scott A.; Richardson, James W.; Poeppelmeier, Kenneth R.
In: Chemistry of Materials, Vol. 22, No. 10, 25.05.2010, p. 3283-3289.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structural and chemical evolution of the SOFC anode La 0.30Sr0.70Fe0.70Cr0.30O 3-δ upon reduction and oxidation
T2 - An in situ neutron diffraction study
AU - Haag, Jacob M.
AU - Barnett, Scott A.
AU - Richardson, James W.
AU - Poeppelmeier, Kenneth R
PY - 2010/5/25
Y1 - 2010/5/25
N2 - Although some perovskite oxides have been shown to be stable solid oxide fuel cell (SOFC) anodes, the actual crystal structure of these materials under operating conditions is largely unknown. In this paper, the structural evolution of the SOFC anode La0.30Sr0.70Fe0.70Cr 0.30O3-δ was studied at 800 and 900 °C (similar to SOFC operating temperatures) in progressively reducing and oxidizing environments. The perovskite was shown to be stable down to a pO2 of 10-20 atm at 800 °C and a pO2 of 10-18 atm at 900 °C, at which point a spinel phase formed. Further reduction led to the formation of Fe metal. The phase separation of La0.30Sr 0.70Fe0.70Cr0.30O3-δ was also shown to be completely reversible with an increase in the partial oxygen pressure and reoxidation of the sample.
AB - Although some perovskite oxides have been shown to be stable solid oxide fuel cell (SOFC) anodes, the actual crystal structure of these materials under operating conditions is largely unknown. In this paper, the structural evolution of the SOFC anode La0.30Sr0.70Fe0.70Cr 0.30O3-δ was studied at 800 and 900 °C (similar to SOFC operating temperatures) in progressively reducing and oxidizing environments. The perovskite was shown to be stable down to a pO2 of 10-20 atm at 800 °C and a pO2 of 10-18 atm at 900 °C, at which point a spinel phase formed. Further reduction led to the formation of Fe metal. The phase separation of La0.30Sr 0.70Fe0.70Cr0.30O3-δ was also shown to be completely reversible with an increase in the partial oxygen pressure and reoxidation of the sample.
UR - http://www.scopus.com/inward/record.url?scp=77952492334&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=77952492334&partnerID=8YFLogxK
U2 - 10.1021/cm100609e
DO - 10.1021/cm100609e
M3 - Article
AN - SCOPUS:77952492334
VL - 22
SP - 3283
EP - 3289
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 10
ER -