Structural evolution during the reduction of chemically derived graphene oxide

Akbar Bagri, Cecilia Mattevi, Muge Acik, Yves J. Chabal, Manish Chhowalla, Vivek B. Shenoy

Research output: Contribution to journalArticle

1069 Citations (Scopus)

Abstract

The excellent electrical, optical and mechanical properties of graphene have driven the search to find methods for its large-scale production, but established procedures (such as mechanical exfoliation or chemical vapour deposition) are not ideal for the manufacture of processable graphene sheets. An alternative method is the reduction of graphene oxide, a material that shares the same atomically thin structural framework as graphene, but bears oxygen-containing functional groups. Here we use molecular dynamics simulations to study the atomistic structure of progressively reduced graphene oxide. The chemical changes of oxygen-containing functional groups on the annealing of graphene oxide are elucidated and the simulations reveal the formation of highly stable carbonyl and ether groups that hinder its complete reduction to graphene. The calculations are supported by infrared and X-ray photoelectron spectroscopy measurements. Finally, more effective reduction treatments to improve the reduction of graphene oxide are proposed.

Original languageEnglish
Pages (from-to)581-587
Number of pages7
JournalNature Chemistry
Volume2
Issue number7
DOIs
Publication statusPublished - Jul 2010

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Oxides
Graphene
Functional groups
Oxygen
Ether
Molecular dynamics
Chemical vapor deposition
Ethers
Electric properties
X ray photoelectron spectroscopy
Optical properties
Annealing
Infrared radiation
Mechanical properties
Computer simulation

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Structural evolution during the reduction of chemically derived graphene oxide. / Bagri, Akbar; Mattevi, Cecilia; Acik, Muge; Chabal, Yves J.; Chhowalla, Manish; Shenoy, Vivek B.

In: Nature Chemistry, Vol. 2, No. 7, 07.2010, p. 581-587.

Research output: Contribution to journalArticle

Bagri, A, Mattevi, C, Acik, M, Chabal, YJ, Chhowalla, M & Shenoy, VB 2010, 'Structural evolution during the reduction of chemically derived graphene oxide', Nature Chemistry, vol. 2, no. 7, pp. 581-587. https://doi.org/10.1038/nchem.686
Bagri, Akbar ; Mattevi, Cecilia ; Acik, Muge ; Chabal, Yves J. ; Chhowalla, Manish ; Shenoy, Vivek B. / Structural evolution during the reduction of chemically derived graphene oxide. In: Nature Chemistry. 2010 ; Vol. 2, No. 7. pp. 581-587.
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