Structural, optical, and transport properties of α- And β-Ag 3VO 4

V. Cloet, A. Raw, Kenneth R Poeppelmeier, G. Trimarchi, H. Peng, J. Im, Arthur J Freeman, N. H. Perry, Thomas O Mason, A. Zakutayev, P. F. Ndione, D. S. Ginley, J. D. Perkins

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

The structures of α- and β-Ag 3VO 4 were studied via single-crystal X-ray diffraction (XRD). The transition from α-phase to β-phase was found to occur at 110 °C. Single-crystal XRD revealed that the integrity of the single crystals was maintained as Ag 3VO 4 reversibly transitioned between α-Ag 3VO 4 and β-Ag 3VO 4. The optical and electrical properties of polycrystalline α-Ag 3VO 4 were studied by diffuse reflectance spectroscopy and impedance spectroscopy. In order to assess the optical and electrical properties of β-Ag 3VO 4, in situ measurements were performed above the phase-transition temperature. Thin films of α-Ag 3VO 4 were prepared by combinatorial sputtering and pulsed laser deposition (PLD). The crystallographic, optical, and electrical conductivity properties of the α-Ag 3VO 4 thin films were compared with the bulk properties.

Original languageEnglish
Pages (from-to)3346-3354
Number of pages9
JournalChemistry of Materials
Volume24
Issue number17
DOIs
Publication statusPublished - Sep 11 2012

Fingerprint

Transport properties
Structural properties
Optical properties
Single crystals
Electric properties
Spectroscopy
Optical conductivity
X ray diffraction
Thin films
Pulsed laser deposition
Superconducting transition temperature
Sputtering
Phase transitions
Electric Conductivity

Keywords

  • α-Ag VO
  • β-Ag VO
  • electrical conductivity
  • single crystal
  • thin film

ASJC Scopus subject areas

  • Materials Chemistry
  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Cloet, V., Raw, A., Poeppelmeier, K. R., Trimarchi, G., Peng, H., Im, J., ... Perkins, J. D. (2012). Structural, optical, and transport properties of α- And β-Ag 3VO 4 Chemistry of Materials, 24(17), 3346-3354. https://doi.org/10.1021/cm301119c

Structural, optical, and transport properties of α- And β-Ag 3VO 4 . / Cloet, V.; Raw, A.; Poeppelmeier, Kenneth R; Trimarchi, G.; Peng, H.; Im, J.; Freeman, Arthur J; Perry, N. H.; Mason, Thomas O; Zakutayev, A.; Ndione, P. F.; Ginley, D. S.; Perkins, J. D.

In: Chemistry of Materials, Vol. 24, No. 17, 11.09.2012, p. 3346-3354.

Research output: Contribution to journalArticle

Cloet, V, Raw, A, Poeppelmeier, KR, Trimarchi, G, Peng, H, Im, J, Freeman, AJ, Perry, NH, Mason, TO, Zakutayev, A, Ndione, PF, Ginley, DS & Perkins, JD 2012, 'Structural, optical, and transport properties of α- And β-Ag 3VO 4 ', Chemistry of Materials, vol. 24, no. 17, pp. 3346-3354. https://doi.org/10.1021/cm301119c
Cloet, V. ; Raw, A. ; Poeppelmeier, Kenneth R ; Trimarchi, G. ; Peng, H. ; Im, J. ; Freeman, Arthur J ; Perry, N. H. ; Mason, Thomas O ; Zakutayev, A. ; Ndione, P. F. ; Ginley, D. S. ; Perkins, J. D. / Structural, optical, and transport properties of α- And β-Ag 3VO 4 In: Chemistry of Materials. 2012 ; Vol. 24, No. 17. pp. 3346-3354.
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