Abstract
Who can split water? Two polymorphs of nanocrystalline cubic spinel and rhombohedral layered lithium cobalt oxides have been prepared and their application in the photocatalytic oxidation of water examined. The main factor that determines the catalytic activity of the different phases is the presence of a Co 4O 4 cubic core, which is present in the cubic form of the catalyst, but not in the layered structure (see scheme).
| Original language | English |
|---|---|
| Pages (from-to) | 1616-1619 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 51 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - Feb 13 2012 |
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Keywords
- cobalt
- heterogeneous catalysis
- lithium
- spinels
- water splitting
ASJC Scopus subject areas
- Chemistry(all)
- Catalysis
Cite this
Structural requirements in lithium cobalt oxides for the catalytic oxidation of water. / Gardner, Graeme P.; Go, Yong Bok; Robinson, David M.; Smith, Paul F.; Hadermann, Joke; Abakumov, Artem; Greenblatt, Martha; Dismukes, G Charles.
In: Angewandte Chemie - International Edition, Vol. 51, No. 7, 13.02.2012, p. 1616-1619.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structural requirements in lithium cobalt oxides for the catalytic oxidation of water
AU - Gardner, Graeme P.
AU - Go, Yong Bok
AU - Robinson, David M.
AU - Smith, Paul F.
AU - Hadermann, Joke
AU - Abakumov, Artem
AU - Greenblatt, Martha
AU - Dismukes, G Charles
PY - 2012/2/13
Y1 - 2012/2/13
N2 - Who can split water? Two polymorphs of nanocrystalline cubic spinel and rhombohedral layered lithium cobalt oxides have been prepared and their application in the photocatalytic oxidation of water examined. The main factor that determines the catalytic activity of the different phases is the presence of a Co 4O 4 cubic core, which is present in the cubic form of the catalyst, but not in the layered structure (see scheme).
AB - Who can split water? Two polymorphs of nanocrystalline cubic spinel and rhombohedral layered lithium cobalt oxides have been prepared and their application in the photocatalytic oxidation of water examined. The main factor that determines the catalytic activity of the different phases is the presence of a Co 4O 4 cubic core, which is present in the cubic form of the catalyst, but not in the layered structure (see scheme).
KW - cobalt
KW - heterogeneous catalysis
KW - lithium
KW - spinels
KW - water splitting
UR - http://www.scopus.com/inward/record.url?scp=84863393354&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84863393354&partnerID=8YFLogxK
U2 - 10.1002/anie.201107625
DO - 10.1002/anie.201107625
M3 - Article
VL - 51
SP - 1616
EP - 1619
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 7
ER -