Structural similarities among oxygen-deficient perovskites

Mark T. Anderson; John T. Vaughey; Kenneth R Poeppelmeier

Structural similarities among oxygen-deficient perovskites

Mark T. Anderson, John T. Vaughey, Kenneth R Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article › peer-review

156 Citations (Scopus)

Abstract

A general review and description is given of vacancy patterns in oxygen-deficient perovskites A_mB_mO_3m-x. Thirteen compounds that contain unique oxygen vacancy patterns and that adopt structures related to cubic closest packing are examined in detail: m = 2, x = 1, Ca₂Mn₂O₅, LaSrCuGaO₅, La₂Ni₂O₅, LaSrCuAlO₅, YBaCuFeO₅, Ca₂Co₂O₅; m = 3, x = 1, 2, or 3, LaBa₂-Cu₂TaO₈;, LaSr₂Fe₃O₈, YBa₂Cu₃O₇, LnSr₂Cu₂GaO₇, YBa₂Cu₃O₆; m = 4, x = 1, Ba₂La₂Cu₂Sn₂O₁₁ and Ca₄Ti₂Fe₂O₁₁. The structural similarity among the compounds is stressed by the presentation and examination of AO_3-x slices. The influence of the A and B cations on the manner in which successive AO_3-x layers are stacked is presented and discussed.

Original language	English
Pages (from-to)	151-165
Number of pages	15
Journal	Chemistry of Materials
Volume	5
Issue number	2
Publication status	Published - 1993

ASJC Scopus subject areas

Materials Chemistry
Materials Science(all)

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title = "Structural similarities among oxygen-deficient perovskites",

abstract = "A general review and description is given of vacancy patterns in oxygen-deficient perovskites AmBmO3m-x. Thirteen compounds that contain unique oxygen vacancy patterns and that adopt structures related to cubic closest packing are examined in detail: m = 2, x = 1, Ca2Mn2O5, LaSrCuGaO5, La2Ni2O5, LaSrCuAlO5, YBaCuFeO5, Ca2Co2O5; m = 3, x = 1, 2, or 3, LaBa2-Cu2TaO8;, LaSr2Fe3O8, YBa2Cu3O7, LnSr2Cu2GaO7, YBa2Cu3O6; m = 4, x = 1, Ba2La2Cu2Sn2O11 and Ca4Ti2Fe2O11. The structural similarity among the compounds is stressed by the presentation and examination of AO3-x slices. The influence of the A and B cations on the manner in which successive AO3-x layers are stacked is presented and discussed.",

author = "Anderson, {Mark T.} and Vaughey, {John T.} and Poeppelmeier, {Kenneth R}",

year = "1993",

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journal = "Chemistry of Materials",

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T1 - Structural similarities among oxygen-deficient perovskites

AU - Anderson, Mark T.

AU - Vaughey, John T.

AU - Poeppelmeier, Kenneth R

PY - 1993

Y1 - 1993

N2 - A general review and description is given of vacancy patterns in oxygen-deficient perovskites AmBmO3m-x. Thirteen compounds that contain unique oxygen vacancy patterns and that adopt structures related to cubic closest packing are examined in detail: m = 2, x = 1, Ca2Mn2O5, LaSrCuGaO5, La2Ni2O5, LaSrCuAlO5, YBaCuFeO5, Ca2Co2O5; m = 3, x = 1, 2, or 3, LaBa2-Cu2TaO8;, LaSr2Fe3O8, YBa2Cu3O7, LnSr2Cu2GaO7, YBa2Cu3O6; m = 4, x = 1, Ba2La2Cu2Sn2O11 and Ca4Ti2Fe2O11. The structural similarity among the compounds is stressed by the presentation and examination of AO3-x slices. The influence of the A and B cations on the manner in which successive AO3-x layers are stacked is presented and discussed.

AB - A general review and description is given of vacancy patterns in oxygen-deficient perovskites AmBmO3m-x. Thirteen compounds that contain unique oxygen vacancy patterns and that adopt structures related to cubic closest packing are examined in detail: m = 2, x = 1, Ca2Mn2O5, LaSrCuGaO5, La2Ni2O5, LaSrCuAlO5, YBaCuFeO5, Ca2Co2O5; m = 3, x = 1, 2, or 3, LaBa2-Cu2TaO8;, LaSr2Fe3O8, YBa2Cu3O7, LnSr2Cu2GaO7, YBa2Cu3O6; m = 4, x = 1, Ba2La2Cu2Sn2O11 and Ca4Ti2Fe2O11. The structural similarity among the compounds is stressed by the presentation and examination of AO3-x slices. The influence of the A and B cations on the manner in which successive AO3-x layers are stacked is presented and discussed.

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