Structural transformations during formation of quasi-amorphous BaTiO 3

David Ehre, Hagai Cohen, Vera Lyahovitskaya, Alexander Tagantsev, Igor Lubomirsky

Research output: Contribution to journalArticle

14 Citations (Scopus)

Abstract

A model of structural transformations of amorphous into quasi-amorphous BaTiO3 is suggested. The model is based on previously published data and on X-ray photoelectron spectroscopy data presented in the current report Both amorphous and quasi-amorphous phases of BaTiO3 are made up of a network of slightly distorted TiO6 octahedra connected in three different ways: by apices (akin to perovskite), edges, and faces. Ba ions in these phases are located in the voids between the octahedra, which is a nonperovskite environment. These data also suggest that Ba ions compensate electrical-charge imbalance incurred by randomly connected octahedra and, thereby, stabilize the TiO6 network. Upon heating, the edge-to-edge and face-to-face connections between TiO6 octahedra are severed and then reconnected via apices. Severing the connections between TiO6 octahedra requires a volume increase, suppression of which keeps some of the edge-to-edge and face-to-face connections intact. Transformation of the amorphous thin films into the quasi-amorphous phase occurs during pulling through a steep temperature gradient. During this process, the volume increase is inhomogeneous and causes both highly anisotropic strain and a strain gradient. The strain gradient favors breaking those connections, which aligns the distorted TiO6 octahedra along the direction of the gradient. As a result, the structure becomes not only anisotropic and non-centrosymmetric, but also acquires macroscopic polarization. Other compounds may also form a quasi-amorphous phase, providing that they satisfy the set of conditions derived from the suggested model.

Original languageEnglish
Pages (from-to)1204-1208
Number of pages5
JournalAdvanced Functional Materials
Volume17
Issue number7
DOIs
Publication statusPublished - May 7 2007

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gradients
apexes
Ions
pulling
Amorphous films
voids
temperature gradients
ions
Perovskite
Thermal gradients
retarding
photoelectron spectroscopy
X ray photoelectron spectroscopy
heating
Polarization
causes
Heating
polarization
Thin films
thin films

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Science(all)
  • Condensed Matter Physics
  • Physics and Astronomy (miscellaneous)

Cite this

Structural transformations during formation of quasi-amorphous BaTiO 3 . / Ehre, David; Cohen, Hagai; Lyahovitskaya, Vera; Tagantsev, Alexander; Lubomirsky, Igor.

In: Advanced Functional Materials, Vol. 17, No. 7, 07.05.2007, p. 1204-1208.

Research output: Contribution to journalArticle

Ehre, David ; Cohen, Hagai ; Lyahovitskaya, Vera ; Tagantsev, Alexander ; Lubomirsky, Igor. / Structural transformations during formation of quasi-amorphous BaTiO 3 . In: Advanced Functional Materials. 2007 ; Vol. 17, No. 7. pp. 1204-1208.
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