Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11

Xiandong Wang, Douglas A. Vander Griend, Charlotte L. Stern, Kenneth R Poeppelmeier

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Abstract

FeMg2V3O11 crystals grown from a MgO/Fe2O3/V2O5 melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn2V3O11 crystals grown from a ZnO/Fe2O3/V2O5 melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn2V3O11, and susceptibility measurements reveal that all iron is high spin d5. In FeMg2V3O11, Fe3 is distributed non-statistically with Mg2+ on octahedral and bipyramidal sites. In FeZn2V3O11, Fe3+ is found only on the octahedral sites and Zn2+ exclusively occupies the bipyramidal sites.

Original languageEnglish
Pages (from-to)119-124
Number of pages6
JournalJournal of Alloys and Compounds
Volume298
Issue number1-2
DOIs
Publication statusPublished - Feb 28 2000

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Vanadates
Cations
Positive ions
Crystals
Iron
vanadium pentoxide

ASJC Scopus subject areas

  • Metals and Alloys

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Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11 . / Wang, Xiandong; Vander Griend, Douglas A.; Stern, Charlotte L.; Poeppelmeier, Kenneth R.

In: Journal of Alloys and Compounds, Vol. 298, No. 1-2, 28.02.2000, p. 119-124.

Research output: Contribution to journal › Article

Wang, X, Vander Griend, DA, Stern, CL & Poeppelmeier, KR 2000, 'Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11 ', Journal of Alloys and Compounds, vol. 298, no. 1-2, pp. 119-124. https://doi.org/10.1016/S0925-8388(99)00662-3
Wang X, Vander Griend DA, Stern CL, Poeppelmeier KR. Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11 Journal of Alloys and Compounds. 2000 Feb 28;298(1-2):119-124. https://doi.org/10.1016/S0925-8388(99)00662-3
Wang, Xiandong ; Vander Griend, Douglas A. ; Stern, Charlotte L. ; Poeppelmeier, Kenneth R. / Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11 In: Journal of Alloys and Compounds. 2000 ; Vol. 298, No. 1-2. pp. 119-124.
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abstract = "FeMg2V3O11 crystals grown from a MgO/Fe2O3/V2O5 melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn2V3O11 crystals grown from a ZnO/Fe2O3/V2O5 melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn2V3O11, and susceptibility measurements reveal that all iron is high spin d5. In FeMg2V3O11, Fe3 is distributed non-statistically with Mg2+ on octahedral and bipyramidal sites. In FeZn2V3O11, Fe3+ is found only on the octahedral sites and Zn2+ exclusively occupies the bipyramidal sites.",
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