Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11

Xiandong Wang; Douglas A. Vander Griend; Charlotte L. Stern; Kenneth R Poeppelmeier

doi:10.1016/S0925-8388(99)00662-3

Structure and cation distribution of new ternary vanadates FeMg₂V₃O₁₁ and FeZn₂V₃O₁₁

Xiandong Wang, Douglas A. Vander Griend, Charlotte L. Stern, Kenneth R Poeppelmeier

Northwestern University

Research output: Contribution to journal › Article

62 Citations (Scopus)

Abstract

FeMg₂V₃O₁₁ crystals grown from a MgO/Fe₂O₃/V₂O₅ melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn₂V₃O₁₁ crystals grown from a ZnO/Fe₂O₃/V₂O₅ melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn₂V₃O₁₁, and susceptibility measurements reveal that all iron is high spin d⁵. In FeMg₂V₃O₁₁, Fe³ is distributed non-statistically with Mg²⁺ on octahedral and bipyramidal sites. In FeZn₂V₃O₁₁, Fe³⁺ is found only on the octahedral sites and Zn²⁺ exclusively occupies the bipyramidal sites.

Original language	English
Pages (from-to)	119-124
Number of pages	6
Journal	Journal of Alloys and Compounds
Volume	298
Issue number	1-2
DOIs	https://doi.org/10.1016/S0925-8388(99)00662-3
Publication status	Published - Feb 28 2000

ASJC Scopus subject areas

Metals and Alloys

Access to Document

10.1016/S0925-8388(99)00662-3

Fingerprint Dive into the research topics of 'Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11'. Together they form a unique fingerprint.

Cite this

Wang, X., Vander Griend, D. A., Stern, C. L., & Poeppelmeier, K. R. (2000). Structure and cation distribution of new ternary vanadates FeMg₂V₃O₁₁ and FeZn₂V₃O₁₁ Journal of Alloys and Compounds, 298(1-2), 119-124. https://doi.org/10.1016/S0925-8388(99)00662-3

@article{a801ebf3b2124eb8b3fdebcdd985101b,

title = "Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11 ",

abstract = "FeMg2V3O11 crystals grown from a MgO/Fe2O3/V2O5 melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn2V3O11 crystals grown from a ZnO/Fe2O3/V2O5 melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn2V3O11, and susceptibility measurements reveal that all iron is high spin d5. In FeMg2V3O11, Fe3 is distributed non-statistically with Mg2+ on octahedral and bipyramidal sites. In FeZn2V3O11, Fe3+ is found only on the octahedral sites and Zn2+ exclusively occupies the bipyramidal sites.",

author = "Xiandong Wang and {Vander Griend}, {Douglas A.} and Stern, {Charlotte L.} and Poeppelmeier, {Kenneth R}",

year = "2000",

month = feb,

day = "28",

doi = "10.1016/S0925-8388(99)00662-3",

language = "English",

volume = "298",

pages = "119--124",

journal = "Journal of Alloys and Compounds",

issn = "0925-8388",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Structure and cation distribution of new ternary vanadates FeMg2V3O11 and FeZn2V3O11

AU - Wang, Xiandong

AU - Vander Griend, Douglas A.

AU - Stern, Charlotte L.

AU - Poeppelmeier, Kenneth R

PY - 2000/2/28

Y1 - 2000/2/28

N2 - FeMg2V3O11 crystals grown from a MgO/Fe2O3/V2O5 melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn2V3O11 crystals grown from a ZnO/Fe2O3/V2O5 melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn2V3O11, and susceptibility measurements reveal that all iron is high spin d5. In FeMg2V3O11, Fe3 is distributed non-statistically with Mg2+ on octahedral and bipyramidal sites. In FeZn2V3O11, Fe3+ is found only on the octahedral sites and Zn2+ exclusively occupies the bipyramidal sites.

AB - FeMg2V3O11 crystals grown from a MgO/Fe2O3/V2O5 melt crystallize in the triclinic space group P-1 with parameters: a = 6.434(1) angstroms, b = 6.806(1) angstroms, c = 10.085(1) angstroms, α = 97.44(1)°, β = 103.44(1)°, γ = 101.56(1)° and Z = 2. FeZn2V3O11 crystals grown from a ZnO/Fe2O3/V2O5 melt also crystallize in P-1 with similar parameters: a = 6.455(1) angstroms, b = 6.834(1) angstroms, c = 9.988(1) angstroms, α = 97.65(1)°, β = 102.61(1)°, γ = 101.26(1)° and Z = 2. Both are isostructural with GaZn2V3O11, and susceptibility measurements reveal that all iron is high spin d5. In FeMg2V3O11, Fe3 is distributed non-statistically with Mg2+ on octahedral and bipyramidal sites. In FeZn2V3O11, Fe3+ is found only on the octahedral sites and Zn2+ exclusively occupies the bipyramidal sites.

UR - http://www.scopus.com/inward/record.url?scp=0034135322&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0034135322&partnerID=8YFLogxK

U2 - 10.1016/S0925-8388(99)00662-3

DO - 10.1016/S0925-8388(99)00662-3

M3 - Article

AN - SCOPUS:0034135322

VL - 298

SP - 119

EP - 124

JO - Journal of Alloys and Compounds

JF - Journal of Alloys and Compounds

SN - 0925-8388

IS - 1-2

ER -