Abstract
The compound K14Cd9Tl21 has been prepared by fusion of the elements in a tantalum reactor followed by slow cooling at the rate of 6 per hour to enable crystal growth. The X-ray crystal structure (hexagonal, P62m; a = 9.884(3),c= 17.173(5) Å; Z= 2) was refined to reliability factors of R1 = 5.09, wR2 = 11.64%. The anionic substructure contains both isolated clusters of Tl11/7- and a layered network based on Cd5Tl2 pentagonal bipyramids. The structure electron count relationship for the Tl11/7- cluster was analyzed in detail. The Cd9Tl10/7- layers are found to confer metallic properties to the material, and the bonding within such layers is found to be highly delocalized.
| Original language | English |
|---|---|
| Pages (from-to) | 799-806 |
| Number of pages | 8 |
| Journal | Chemistry - A European Journal |
| Volume | 3 |
| Issue number | 5 |
| Publication status | Published - May 1997 |
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Keywords
- cadmium
- clusters
- layered compounds
- semiempirical calculations
- thallium
- Zintl phases
ASJC Scopus subject areas
- Chemistry(all)
Cite this
Structure and chemical bonding in K14Cd9Tl21, a compound containing both isolated Tl11/7- clusters and (∞)/2([Cd9Tl10/7-] metallic layers. / Tillard-Charbonnel, Monique; Chahine, Abdelkrim; Belin, Claude; Rousseau, Roger; Canadell, Enric.
In: Chemistry - A European Journal, Vol. 3, No. 5, 05.1997, p. 799-806.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Structure and chemical bonding in K14Cd9Tl21, a compound containing both isolated Tl11/7- clusters and (∞)/2([Cd9Tl10/7-] metallic layers
AU - Tillard-Charbonnel, Monique
AU - Chahine, Abdelkrim
AU - Belin, Claude
AU - Rousseau, Roger
AU - Canadell, Enric
PY - 1997/5
Y1 - 1997/5
N2 - The compound K14Cd9Tl21 has been prepared by fusion of the elements in a tantalum reactor followed by slow cooling at the rate of 6 per hour to enable crystal growth. The X-ray crystal structure (hexagonal, P62m; a = 9.884(3),c= 17.173(5) Å; Z= 2) was refined to reliability factors of R1 = 5.09, wR2 = 11.64%. The anionic substructure contains both isolated clusters of Tl11/7- and a layered network based on Cd5Tl2 pentagonal bipyramids. The structure electron count relationship for the Tl11/7- cluster was analyzed in detail. The Cd9Tl10/7- layers are found to confer metallic properties to the material, and the bonding within such layers is found to be highly delocalized.
AB - The compound K14Cd9Tl21 has been prepared by fusion of the elements in a tantalum reactor followed by slow cooling at the rate of 6 per hour to enable crystal growth. The X-ray crystal structure (hexagonal, P62m; a = 9.884(3),c= 17.173(5) Å; Z= 2) was refined to reliability factors of R1 = 5.09, wR2 = 11.64%. The anionic substructure contains both isolated clusters of Tl11/7- and a layered network based on Cd5Tl2 pentagonal bipyramids. The structure electron count relationship for the Tl11/7- cluster was analyzed in detail. The Cd9Tl10/7- layers are found to confer metallic properties to the material, and the bonding within such layers is found to be highly delocalized.
KW - cadmium
KW - clusters
KW - layered compounds
KW - semiempirical calculations
KW - thallium
KW - Zintl phases
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UR - http://www.scopus.com/inward/citedby.url?scp=0031011905&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0031011905
VL - 3
SP - 799
EP - 806
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 5
ER -