Structure and ion transport in polymer-salt complexes

D. F. Shriver, B. L. Papke, Mark A Ratner, R. Dupon, T. Wong, M. Brodwin

Research output: Contribution to journalArticle

142 Citations (Scopus)

Abstract

Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.

Original languageEnglish
Pages (from-to)83-88
Number of pages6
JournalSolid State Ionics
Volume5
Issue numberC
DOIs
Publication statusPublished - 1981

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

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    Shriver, D. F., Papke, B. L., Ratner, M. A., Dupon, R., Wong, T., & Brodwin, M. (1981). Structure and ion transport in polymer-salt complexes. Solid State Ionics, 5(C), 83-88. https://doi.org/10.1016/0167-2738(81)90199-5