Structure and ion transport in polymer-salt complexes

D. F. Shriver, B. L. Papke, Mark A Ratner, R. Dupon, T. Wong, M. Brodwin

Research output: Contribution to journalArticle

137 Citations (Scopus)

Abstract

Polymer electrolytes based on alkali metal complexes of polyethers and cross-linked polyethers have significant cation mobility, which appears to arise from large-amplitude motions of the polymer. High chain flexibility not only promotes ion transport but it also is important for the initial formation of polymer-salt complexes. Several new polymer electrolyte systems are discussed which contain flexible polymer backbones and high concentrations of polar groups.

Original languageEnglish
Pages (from-to)83-88
Number of pages6
JournalSolid State Ionics
Volume5
Issue numberC
DOIs
Publication statusPublished - 1981

Fingerprint

Polymers
Salts
Ions
salts
polymers
Polyethers
ions
Electrolytes
electrolytes
Alkali Metals
Coordination Complexes
Alkali metals
Metal complexes
alkali metals
Cations
flexibility
Positive ions
cations

ASJC Scopus subject areas

  • Electrochemistry
  • Physical and Theoretical Chemistry
  • Energy Engineering and Power Technology
  • Materials Chemistry
  • Condensed Matter Physics

Cite this

Shriver, D. F., Papke, B. L., Ratner, M. A., Dupon, R., Wong, T., & Brodwin, M. (1981). Structure and ion transport in polymer-salt complexes. Solid State Ionics, 5(C), 83-88. https://doi.org/10.1016/0167-2738(81)90199-5

Structure and ion transport in polymer-salt complexes. / Shriver, D. F.; Papke, B. L.; Ratner, Mark A; Dupon, R.; Wong, T.; Brodwin, M.

In: Solid State Ionics, Vol. 5, No. C, 1981, p. 83-88.

Research output: Contribution to journalArticle

Shriver, DF, Papke, BL, Ratner, MA, Dupon, R, Wong, T & Brodwin, M 1981, 'Structure and ion transport in polymer-salt complexes', Solid State Ionics, vol. 5, no. C, pp. 83-88. https://doi.org/10.1016/0167-2738(81)90199-5
Shriver, D. F. ; Papke, B. L. ; Ratner, Mark A ; Dupon, R. ; Wong, T. ; Brodwin, M. / Structure and ion transport in polymer-salt complexes. In: Solid State Ionics. 1981 ; Vol. 5, No. C. pp. 83-88.
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