Structure and magnetic properties of Pb2Cu3B 4O11

A new copper borate featuring [Cu3O 8]10- units

Shilie Pan, Byron Watkins, Jared P. Smit, Michael R. Marvel, Ian Saratovsky, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

Pb2Cu3B4O11 crystallizes in the monoclinic space group P2/n (No. 13) with a = 6.8016(15) Å, b = 4.7123(10) Å, c = 14.614(3) Å, β = 97.089(3)°, and Z = 2. The crystal structure consists of infinite [Cu3O8] 10- zigzag chains of alternating dimers and monomers. The magnetic susceptibility and specific heat capacity show spin-gap and Curie-Weiss behaviors that can be explained by a model of Cu(2)-Cu(2) dimers and isolated or weakly coupled Cu(1) monomers.

Original languageEnglish
Pages (from-to)3851-3855
Number of pages5
JournalInorganic Chemistry
Volume46
Issue number10
DOIs
Publication statusPublished - May 14 2007

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Borates
borates
Dimers
Specific heat
Copper
Magnetic properties
monomers
Monomers
dimers
specific heat
magnetic properties
copper
Magnetic susceptibility
Crystal structure
magnetic permeability
heat
crystal structure

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Structure and magnetic properties of Pb2Cu3B 4O11 : A new copper borate featuring [Cu3O 8]10- units. / Pan, Shilie; Watkins, Byron; Smit, Jared P.; Marvel, Michael R.; Saratovsky, Ian; Poeppelmeier, Kenneth R.

In: Inorganic Chemistry, Vol. 46, No. 10, 14.05.2007, p. 3851-3855.

Research output: Contribution to journalArticle

Pan, Shilie ; Watkins, Byron ; Smit, Jared P. ; Marvel, Michael R. ; Saratovsky, Ian ; Poeppelmeier, Kenneth R. / Structure and magnetic properties of Pb2Cu3B 4O11 : A new copper borate featuring [Cu3O 8]10- units. In: Inorganic Chemistry. 2007 ; Vol. 46, No. 10. pp. 3851-3855.
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