Submolecular control, spectroscopy and imaging of bond-selective chemistry in single functionalized molecules

Ying Jiang, Qing Huan, Laura Fabris, Guillermo C. Bazan, Wilson Ho

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

One of the key challenges in chemistry is to break and form bonds selectively in complex organic molecules that possess a range of different functional groups. To do this at the single-molecule level not only provides an opportunity to create custom nanoscale devices, but offers opportunities for the in-depth study of how the molecular electronic structure changes in individual reactions. Here we use a scanning tunnelling microscope (STM) to induce a sequence of targeted bond dissociation and formation steps in single thiol-based π-conjugated molecules adsorbed on a NiAl(110) surface. Furthermore, the electronic resonances of the resulting species were measured by spatially resolved electronic spectroscopy at each reaction step. Specifically, the STM was used to cleave individual acetyl groups and to form Au-S bonds by manipulating single Au atoms. A detailed understanding of the Au-S bond and its non-local influence is fundamentally important for determining the electron transport in thiol-based molecular junction.

Original languageEnglish
Pages (from-to)36-41
Number of pages6
JournalNature Chemistry
Volume5
Issue number1
DOIs
Publication statusPublished - Jan 2013

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Spectroscopy
Imaging techniques
Sulfhydryl Compounds
Molecules
Microscopes
Scanning
Molecular electronics
Functional groups
Molecular structure
Electronic structure
Atoms
single bond
Electron Transport

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)

Cite this

Submolecular control, spectroscopy and imaging of bond-selective chemistry in single functionalized molecules. / Jiang, Ying; Huan, Qing; Fabris, Laura; Bazan, Guillermo C.; Ho, Wilson.

In: Nature Chemistry, Vol. 5, No. 1, 01.2013, p. 36-41.

Research output: Contribution to journalArticle

Jiang, Ying ; Huan, Qing ; Fabris, Laura ; Bazan, Guillermo C. ; Ho, Wilson. / Submolecular control, spectroscopy and imaging of bond-selective chemistry in single functionalized molecules. In: Nature Chemistry. 2013 ; Vol. 5, No. 1. pp. 36-41.
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