77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8

A. Goldbach, F. Fayon, T. Vosegaard, M. Wachhold, Mercouri G Kanatzidis, D. Massiot, M. L. Saboungi

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The structure of Rb2[Pd(Se4)2]· Se8 has been investigated using 87Rb magic angle spinning and static NMR and 77Se magic angle spinning NMR. The number and the integrated intensities of the 87Rb and 77Se resonances are in full agreement with the crystallographic structure of the compound. The 87Rb and 77Se nuclear spin interaction parameters have been used to characterize the main structural units of the compound: infinite [Rb(Se8)]xx+ columns and polymeric [Pd(Se 4)2]x2x- sheet anions.

Original languageEnglish
Pages (from-to)6996-7000
Number of pages5
JournalInorganic Chemistry
Volume42
Issue number22
DOIs
Publication statusPublished - Nov 3 2003

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Magic angle spinning
metal spinning
Nuclear magnetic resonance
solid state
nuclear magnetic resonance
nuclear spin
Anions
anions
interactions

ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Goldbach, A., Fayon, F., Vosegaard, T., Wachhold, M., Kanatzidis, M. G., Massiot, D., & Saboungi, M. L. (2003). 77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8. Inorganic Chemistry, 42(22), 6996-7000. https://doi.org/10.1021/ic030074m

77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8. / Goldbach, A.; Fayon, F.; Vosegaard, T.; Wachhold, M.; Kanatzidis, Mercouri G; Massiot, D.; Saboungi, M. L.

In: Inorganic Chemistry, Vol. 42, No. 22, 03.11.2003, p. 6996-7000.

Research output: Contribution to journalArticle

Goldbach, A, Fayon, F, Vosegaard, T, Wachhold, M, Kanatzidis, MG, Massiot, D & Saboungi, ML 2003, '77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8', Inorganic Chemistry, vol. 42, no. 22, pp. 6996-7000. https://doi.org/10.1021/ic030074m
Goldbach A, Fayon F, Vosegaard T, Wachhold M, Kanatzidis MG, Massiot D et al. 77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8. Inorganic Chemistry. 2003 Nov 3;42(22):6996-7000. https://doi.org/10.1021/ic030074m
Goldbach, A. ; Fayon, F. ; Vosegaard, T. ; Wachhold, M. ; Kanatzidis, Mercouri G ; Massiot, D. ; Saboungi, M. L. / 77Se and 87Rb Solid State NMR Study of the Structure of Rb2[Pd(Se4)2]·Se8. In: Inorganic Chemistry. 2003 ; Vol. 42, No. 22. pp. 6996-7000.
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