Supported Tetrahedral Oxo-Sn Catalyst: Single Site, Two Modes of Catalysis

Evgeny V. Beletskiy, Xianliang Hou, Zhongliang Shen, James R. Gallagher, Jeffrey T. Miller, Yuyang Wu, Tiehu Li, Mayfair C. Kung, Harold H Kung

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

Mild calcination in ozone of a (POSS)-Sn-(POSS) complex grafted on silica generated a heterogenized catalyst that mostly retained the tetrahedral coordination of its homogeneous precursor, as evidenced by spectroscopic characterizations using EXAFS, NMR, UV-vis, and DRIFT. The Sn centers are accessible and uniform and can be quantified by stoichiometric pyridine poisoning. This Sn-catalyst is active in hydride transfer reactions as a typical solid Lewis acid. However, the Sn centers can also create Brønsted acidity with alcohol by binding the alcohol strongly as alkoxide and transferring the hydroxyl H to the neighboring Sn-O-Si bond. The resulting acidic silanol is active in epoxide ring opening and acetalization reactions.

Original languageEnglish
Pages (from-to)4294-4297
Number of pages4
JournalJournal of the American Chemical Society
Volume138
Issue number13
DOIs
Publication statusPublished - Apr 20 2016

ASJC Scopus subject areas

  • Chemistry(all)
  • Catalysis
  • Biochemistry
  • Colloid and Surface Chemistry

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    Beletskiy, E. V., Hou, X., Shen, Z., Gallagher, J. R., Miller, J. T., Wu, Y., Li, T., Kung, M. C., & Kung, H. H. (2016). Supported Tetrahedral Oxo-Sn Catalyst: Single Site, Two Modes of Catalysis. Journal of the American Chemical Society, 138(13), 4294-4297. https://doi.org/10.1021/jacs.5b13436