Abstract
Two two-dimensional coordination complexes, {[Cu4(BTM) 6(OPA)4]·4DMF·3H2O} n (1) and {[Cu(BDTM)(OH)](ClO4)·2H2O} n (2) (BTM = bis(1,2,4-triazol-1-yl)methane, BDTM = bis(3,5-dimethyl-1,2,4- triazol-1-yl)methane, OPA2- = ortho-phthalic dianion, DMF = N,N-dimethylformamide), were synthesized and structurally characterized. Each Cu(II) ion locates in a distorted square pyramidal geometry in 1, in which OPA2- ligands bridge Cu2+ ions along a axis to form a magnetic transmission chain and BTM ligands act as flexible spacers to construct the two-dimensional layer structure. In 2, each Cu2+ ion adopts tetra-coordination geometry to two hydroxyl groups and two triazolyl nitrogen atoms from two different BDTM ligands. Two hydroxyl groups bridge two Cu 2+ ions to form a rhombic diamond, and four BDTM ligands connect four diamonds to form a 36-membered macrocyclic structure with large channels along a axis. Magnetic properties revealed that both OPA2- and OH - mediate anti-ferromagnetic interactions between Cu2+ ions with J = - 0.06(3) and -301.9(2) cm-1 for 1 and 2, respectively.
| Original language | English |
|---|---|
| Pages (from-to) | 911-916 |
| Number of pages | 6 |
| Journal | Structural Chemistry |
| Volume | 19 |
| Issue number | 6 |
| DOIs | |
| Publication status | Published - Dec 2008 |
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Keywords
- Crystal structure
- Magnetic properties
- Self-assembly
ASJC Scopus subject areas
- Condensed Matter Physics
- Physical and Theoretical Chemistry
Cite this
Supramolecular self-assembly of two Cu(II) complexes with 1,2,4-triazole derivatives : Syntheses, crystal structures and magnetic properties. / Zhang, Lei; Ling, Yun; Li, Jing; Gao, Hongyan.
In: Structural Chemistry, Vol. 19, No. 6, 12.2008, p. 911-916.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Supramolecular self-assembly of two Cu(II) complexes with 1,2,4-triazole derivatives
T2 - Syntheses, crystal structures and magnetic properties
AU - Zhang, Lei
AU - Ling, Yun
AU - Li, Jing
AU - Gao, Hongyan
PY - 2008/12
Y1 - 2008/12
N2 - Two two-dimensional coordination complexes, {[Cu4(BTM) 6(OPA)4]·4DMF·3H2O} n (1) and {[Cu(BDTM)(OH)](ClO4)·2H2O} n (2) (BTM = bis(1,2,4-triazol-1-yl)methane, BDTM = bis(3,5-dimethyl-1,2,4- triazol-1-yl)methane, OPA2- = ortho-phthalic dianion, DMF = N,N-dimethylformamide), were synthesized and structurally characterized. Each Cu(II) ion locates in a distorted square pyramidal geometry in 1, in which OPA2- ligands bridge Cu2+ ions along a axis to form a magnetic transmission chain and BTM ligands act as flexible spacers to construct the two-dimensional layer structure. In 2, each Cu2+ ion adopts tetra-coordination geometry to two hydroxyl groups and two triazolyl nitrogen atoms from two different BDTM ligands. Two hydroxyl groups bridge two Cu 2+ ions to form a rhombic diamond, and four BDTM ligands connect four diamonds to form a 36-membered macrocyclic structure with large channels along a axis. Magnetic properties revealed that both OPA2- and OH - mediate anti-ferromagnetic interactions between Cu2+ ions with J = - 0.06(3) and -301.9(2) cm-1 for 1 and 2, respectively.
AB - Two two-dimensional coordination complexes, {[Cu4(BTM) 6(OPA)4]·4DMF·3H2O} n (1) and {[Cu(BDTM)(OH)](ClO4)·2H2O} n (2) (BTM = bis(1,2,4-triazol-1-yl)methane, BDTM = bis(3,5-dimethyl-1,2,4- triazol-1-yl)methane, OPA2- = ortho-phthalic dianion, DMF = N,N-dimethylformamide), were synthesized and structurally characterized. Each Cu(II) ion locates in a distorted square pyramidal geometry in 1, in which OPA2- ligands bridge Cu2+ ions along a axis to form a magnetic transmission chain and BTM ligands act as flexible spacers to construct the two-dimensional layer structure. In 2, each Cu2+ ion adopts tetra-coordination geometry to two hydroxyl groups and two triazolyl nitrogen atoms from two different BDTM ligands. Two hydroxyl groups bridge two Cu 2+ ions to form a rhombic diamond, and four BDTM ligands connect four diamonds to form a 36-membered macrocyclic structure with large channels along a axis. Magnetic properties revealed that both OPA2- and OH - mediate anti-ferromagnetic interactions between Cu2+ ions with J = - 0.06(3) and -301.9(2) cm-1 for 1 and 2, respectively.
KW - Crystal structure
KW - Magnetic properties
KW - Self-assembly
UR - http://www.scopus.com/inward/record.url?scp=56549095491&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=56549095491&partnerID=8YFLogxK
U2 - 10.1007/s11224-008-9375-y
DO - 10.1007/s11224-008-9375-y
M3 - Article
VL - 19
SP - 911
EP - 916
JO - Structural Chemistry
JF - Structural Chemistry
SN - 1040-0400
IS - 6
ER -