Switch of the Rate-Determining Step of Water Oxidation by Spin-Selected Electron Transfer in Spinel Oxides

Shengnan Sun, Yuanmiao Sun, Ye Zhou, Jingjing Shen, Daniel Mandler, Ronny Neumann, Zhichuan J. Xu

Research output: Contribution to journalArticle

Abstract

The 3d transition-metal oxides are a class of promising catalysts for the oxygen evolution reaction (OER) in alkaline media. Manganese-based spinel oxides usually do not show impressive OER performance, and their activity is generally lower than the counterparts containing cobalt. The OER activity and the electronic structure of spinel oxides ZnMn2O4, ZnCo2O4, and the cobalt-substituted ZnMn2O4 were investigated. It has been found that compared to ZnCo2O4, the lower activity of ZnMn2O4 arises from the limitation of spin-selective electron transfer and orbital symmetry restrictions between adsorption of the oxygen species onto the conduction band and the electron transfer from the conduction band to the valence band. The substitution of cobalt into ZnMn2O4 alleviates the spin incompatibility and enables the increase in OER activity.

Original languageEnglish
Pages (from-to)8106-8111
Number of pages6
JournalChemistry of Materials
Volume31
Issue number19
DOIs
Publication statusPublished - Oct 8 2019

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Oxides
Switches
Oxygen
Oxidation
Cobalt
Electrons
Water
Conduction bands
Manganese
Valence bands
Electronic structure
Transition metals
Substitution reactions
spinell
Adsorption
Catalysts

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

Cite this

Switch of the Rate-Determining Step of Water Oxidation by Spin-Selected Electron Transfer in Spinel Oxides. / Sun, Shengnan; Sun, Yuanmiao; Zhou, Ye; Shen, Jingjing; Mandler, Daniel; Neumann, Ronny; Xu, Zhichuan J.

In: Chemistry of Materials, Vol. 31, No. 19, 08.10.2019, p. 8106-8111.

Research output: Contribution to journalArticle

Sun, Shengnan ; Sun, Yuanmiao ; Zhou, Ye ; Shen, Jingjing ; Mandler, Daniel ; Neumann, Ronny ; Xu, Zhichuan J. / Switch of the Rate-Determining Step of Water Oxidation by Spin-Selected Electron Transfer in Spinel Oxides. In: Chemistry of Materials. 2019 ; Vol. 31, No. 19. pp. 8106-8111.
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