Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe

Haijun Wu, Cheng Chang, Dan Feng, Yu Xiao, Xiao Zhang, Yanling Pei, Lei Zheng, Di Wu, Shengkai Gong, Yue Chen, Jiaqing He, Mercouri G Kanatzidis, Li Dong Zhao

Research output: Contribution to journalArticle

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Abstract

Lead chalcogenides are the most efficient thermoelectric materials. In comparison, SnTe, a lead-free analogue of PbTe, exhibits inferior thermoelectric performance due to low Seebeck coefficient and high thermal conductivity. In this report, we show that we can synergistically optimize the electrical and thermal transport properties of SnTe via alloying Mn. We report that the introduction of Mn (0-50%) induces multiple effects on the band structure and microstructure of SnTe: for the former, it can tune the Fermi level and promote the convergence of the two valence bands, concurrently enhancing the Seebeck coefficient; for the latter, it can profoundly modify the microstructure into an all-scale hierarchical architecture (including nanoscale precipitates/MnTe laminates, stacking faults, layered structure, atomic-scale point defects, etc.) to scatter phonons with a broad range of mean free paths, strongly reducing the lattice thermal conductivity. Meanwhile, most significantly, the Mn alloying enlarges the energy gap of the conduction band (C band) and the light valence band (L band), thereby suppressing the bipolar thermal conductivity by increasing the band gap. The integration of these effects yields a high ZT of 1.3 at 900 K for 17% Mn alloyed SnTe.

Original languageEnglish
Pages (from-to)3298-3312
Number of pages15
JournalEnergy and Environmental Science
Volume8
Issue number11
DOIs
Publication statusPublished - Nov 1 2015

Fingerprint

thermal conductivity
Alloying
Transport properties
Thermal conductivity
solubility
Seebeck coefficient
Solubility
Valence bands
microstructure
Energy gap
Lead
Crystal atomic structure
Chalcogenides
Microstructure
Stacking faults
Point defects
Phonons
Fermi level
Conduction bands
stacking

ASJC Scopus subject areas

  • Renewable Energy, Sustainability and the Environment
  • Environmental Chemistry
  • Pollution
  • Nuclear Energy and Engineering

Cite this

Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe. / Wu, Haijun; Chang, Cheng; Feng, Dan; Xiao, Yu; Zhang, Xiao; Pei, Yanling; Zheng, Lei; Wu, Di; Gong, Shengkai; Chen, Yue; He, Jiaqing; Kanatzidis, Mercouri G; Zhao, Li Dong.

In: Energy and Environmental Science, Vol. 8, No. 11, 01.11.2015, p. 3298-3312.

Research output: Contribution to journalArticle

Wu, H, Chang, C, Feng, D, Xiao, Y, Zhang, X, Pei, Y, Zheng, L, Wu, D, Gong, S, Chen, Y, He, J, Kanatzidis, MG & Zhao, LD 2015, 'Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe', Energy and Environmental Science, vol. 8, no. 11, pp. 3298-3312. https://doi.org/10.1039/c5ee02423d
Wu, Haijun ; Chang, Cheng ; Feng, Dan ; Xiao, Yu ; Zhang, Xiao ; Pei, Yanling ; Zheng, Lei ; Wu, Di ; Gong, Shengkai ; Chen, Yue ; He, Jiaqing ; Kanatzidis, Mercouri G ; Zhao, Li Dong. / Synergistically optimized electrical and thermal transport properties of SnTe via alloying high-solubility MnTe. In: Energy and Environmental Science. 2015 ; Vol. 8, No. 11. pp. 3298-3312.
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