Syntheses and structure of hydrothermally prepared CsNiX 3 (X=Cl, Br, I)

Adam D. Raw, James A. Ibers, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

During reinvestigation of the hydrothermal synthesis reported earlier of the compound cesium nickel phosphide, CsNiP, we arrived at a new route to the synthesis of the cesium nickel halide compounds CsNiX 3 (X=Cl, Br, I). The method has also been shown to extend to cobalt and iron compounds. Single crystals of these compounds were synthesized in phosphoric acid in sealed autoclaves. Their structures were determined by single-crystal X-ray diffraction methods. The compounds crystallize in the hexagonal space group P6 3/mmc in the BaNiO 3 structure type. The synthetic method and the resultant crystallographic details for CsNiCl 3 are essentially identical with those reported earlier for the synthesis and structure of CsNiP.

Original languageEnglish
Pages (from-to)34-37
Number of pages4
JournalJournal of Solid State Chemistry
Volume192
DOIs
Publication statusPublished - Aug 2012

Fingerprint

Nickel
Cesium compounds
Cobalt compounds
Single crystals
Iron Compounds
Iron compounds
Cesium
cesium compounds
Hydrothermal synthesis
Autoclaves
Phosphoric acid
synthesis
nickel
cobalt compounds
iron compounds
phosphides
autoclaves
phosphoric acid
single crystals
cesium

Keywords

  • Cesium nickel bromide
  • Cesium nickel chloride
  • Cesium nickel iodide
  • Hydrothermal synthesis
  • X-ray crystal structure

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry

Cite this

Syntheses and structure of hydrothermally prepared CsNiX 3 (X=Cl, Br, I). / Raw, Adam D.; Ibers, James A.; Poeppelmeier, Kenneth R.

In: Journal of Solid State Chemistry, Vol. 192, 08.2012, p. 34-37.

Research output: Contribution to journalArticle

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