Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 (M = Al, Ga)

Fenghua Ding, Matthew L. Nisbet, Hongwei Yu, Weiguo Zhang, Liyuan Chai, P. Shiv Halasyamani, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Single crystals of two new metal tellurates BiMTeO6 (M = Al, Ga) with a honeycomb layered structure were obtained by the molten flux method and characterized. The BiMTeO6 compounds both crystallize into a non-centrosymmetric trigonal space group of P312 (no. 149) with cell parameters of a = 5.0667(8) Å, c = 4.9920(16) Å and a = 5.107(3) Å, c = 4.932(6) Å, respectively. The non-centrosymmetry of BiAlTeO6 and BiGaTeO6 originates from the packing order of the octahedra. In these two structures, TeO6 octahedra and MO6 octahedra share edges and form a honeycomb open-framework with [TeMO6] layers. The layers of [MTeO6] and [BiO6] alternate and are connected along the c-axis by corner-sharing oxygen atoms to form the three-dimensional framework. The chiral compound BiGaTeO6 exhibits a powder second harmonic generation (SHG) response of ∼0.2 times that of potassium dihydrogen phosphate (KDP) and an absorption edge of 355 nm.

Original languageEnglish
Pages (from-to)7950-7956
Number of pages7
JournalInorganic Chemistry
Volume57
Issue number13
DOIs
Publication statusPublished - Jul 2 2018

Fingerprint

Harmonic generation
Powders
Molten materials
Metals
Single crystals
Oxygen
Fluxes
honeycomb structures
Atoms
potassium phosphates
synthesis
oxygen atoms
harmonic generations
single crystals
cells
metals
tellurous acid
potassium phosphate

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this

Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 (M = Al, Ga). / Ding, Fenghua; Nisbet, Matthew L.; Yu, Hongwei; Zhang, Weiguo; Chai, Liyuan; Halasyamani, P. Shiv; Poeppelmeier, Kenneth R.

In: Inorganic Chemistry, Vol. 57, No. 13, 02.07.2018, p. 7950-7956.

Research output: Contribution to journalArticle

Ding, Fenghua ; Nisbet, Matthew L. ; Yu, Hongwei ; Zhang, Weiguo ; Chai, Liyuan ; Halasyamani, P. Shiv ; Poeppelmeier, Kenneth R. / Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 (M = Al, Ga). In: Inorganic Chemistry. 2018 ; Vol. 57, No. 13. pp. 7950-7956.
@article{7fdd64e4f63e43bf9441c69cda401f83,
title = "Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 (M = Al, Ga)",
abstract = "Single crystals of two new metal tellurates BiMTeO6 (M = Al, Ga) with a honeycomb layered structure were obtained by the molten flux method and characterized. The BiMTeO6 compounds both crystallize into a non-centrosymmetric trigonal space group of P312 (no. 149) with cell parameters of a = 5.0667(8) {\AA}, c = 4.9920(16) {\AA} and a = 5.107(3) {\AA}, c = 4.932(6) {\AA}, respectively. The non-centrosymmetry of BiAlTeO6 and BiGaTeO6 originates from the packing order of the octahedra. In these two structures, TeO6 octahedra and MO6 octahedra share edges and form a honeycomb open-framework with [TeMO6]∞ layers. The layers of [MTeO6]∞ and [BiO6]∞ alternate and are connected along the c-axis by corner-sharing oxygen atoms to form the three-dimensional framework. The chiral compound BiGaTeO6 exhibits a powder second harmonic generation (SHG) response of ∼0.2 times that of potassium dihydrogen phosphate (KDP) and an absorption edge of 355 nm.",
author = "Fenghua Ding and Nisbet, {Matthew L.} and Hongwei Yu and Weiguo Zhang and Liyuan Chai and Halasyamani, {P. Shiv} and Poeppelmeier, {Kenneth R}",
year = "2018",
month = "7",
day = "2",
doi = "10.1021/acs.inorgchem.8b01087",
language = "English",
volume = "57",
pages = "7950--7956",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",
number = "13",

}

TY - JOUR

T1 - Syntheses, Structures, and Properties of Non-Centrosymmetric Quaternary Tellurates Bi MTeO6 (M = Al, Ga)

AU - Ding, Fenghua

AU - Nisbet, Matthew L.

AU - Yu, Hongwei

AU - Zhang, Weiguo

AU - Chai, Liyuan

AU - Halasyamani, P. Shiv

AU - Poeppelmeier, Kenneth R

PY - 2018/7/2

Y1 - 2018/7/2

N2 - Single crystals of two new metal tellurates BiMTeO6 (M = Al, Ga) with a honeycomb layered structure were obtained by the molten flux method and characterized. The BiMTeO6 compounds both crystallize into a non-centrosymmetric trigonal space group of P312 (no. 149) with cell parameters of a = 5.0667(8) Å, c = 4.9920(16) Å and a = 5.107(3) Å, c = 4.932(6) Å, respectively. The non-centrosymmetry of BiAlTeO6 and BiGaTeO6 originates from the packing order of the octahedra. In these two structures, TeO6 octahedra and MO6 octahedra share edges and form a honeycomb open-framework with [TeMO6]∞ layers. The layers of [MTeO6]∞ and [BiO6]∞ alternate and are connected along the c-axis by corner-sharing oxygen atoms to form the three-dimensional framework. The chiral compound BiGaTeO6 exhibits a powder second harmonic generation (SHG) response of ∼0.2 times that of potassium dihydrogen phosphate (KDP) and an absorption edge of 355 nm.

AB - Single crystals of two new metal tellurates BiMTeO6 (M = Al, Ga) with a honeycomb layered structure were obtained by the molten flux method and characterized. The BiMTeO6 compounds both crystallize into a non-centrosymmetric trigonal space group of P312 (no. 149) with cell parameters of a = 5.0667(8) Å, c = 4.9920(16) Å and a = 5.107(3) Å, c = 4.932(6) Å, respectively. The non-centrosymmetry of BiAlTeO6 and BiGaTeO6 originates from the packing order of the octahedra. In these two structures, TeO6 octahedra and MO6 octahedra share edges and form a honeycomb open-framework with [TeMO6]∞ layers. The layers of [MTeO6]∞ and [BiO6]∞ alternate and are connected along the c-axis by corner-sharing oxygen atoms to form the three-dimensional framework. The chiral compound BiGaTeO6 exhibits a powder second harmonic generation (SHG) response of ∼0.2 times that of potassium dihydrogen phosphate (KDP) and an absorption edge of 355 nm.

UR - http://www.scopus.com/inward/record.url?scp=85049395875&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85049395875&partnerID=8YFLogxK

U2 - 10.1021/acs.inorgchem.8b01087

DO - 10.1021/acs.inorgchem.8b01087

M3 - Article

AN - SCOPUS:85049395875

VL - 57

SP - 7950

EP - 7956

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

IS - 13

ER -