Abstract
The synthesis, characterization, and reactivity of a series of organoactinide constrained-geometry complexes, (CGC)An(NRR′)2 (CGC = Me2Si(η5-Me4C5)( tBuN); An = Th, 1; An = U, 2; R = R′ = Me, a; R = Et, R′ = Me, b; R = R′ = Et, c), are reported. These complexes are effective precatalysts for intramolecular catalytic hydroamination/cyclization of aminoalkenes and aminoalkynes. Comparisons of structure and reactivity are drawn with previously reported trivalent organolanthanide CGC catalytic systems.
| Original language | English |
|---|---|
| Pages (from-to) | 4836-4838 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 22 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Nov 24 2003 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination. / Stubbert, Bryan D.; Stern, Charlotte L.; Marks, Tobin J.
In: Organometallics, Vol. 22, No. 24, 24.11.2003, p. 4836-4838.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination
AU - Stubbert, Bryan D.
AU - Stern, Charlotte L.
AU - Marks, Tobin J
PY - 2003/11/24
Y1 - 2003/11/24
N2 - The synthesis, characterization, and reactivity of a series of organoactinide constrained-geometry complexes, (CGC)An(NRR′)2 (CGC = Me2Si(η5-Me4C5)( tBuN); An = Th, 1; An = U, 2; R = R′ = Me, a; R = Et, R′ = Me, b; R = R′ = Et, c), are reported. These complexes are effective precatalysts for intramolecular catalytic hydroamination/cyclization of aminoalkenes and aminoalkynes. Comparisons of structure and reactivity are drawn with previously reported trivalent organolanthanide CGC catalytic systems.
AB - The synthesis, characterization, and reactivity of a series of organoactinide constrained-geometry complexes, (CGC)An(NRR′)2 (CGC = Me2Si(η5-Me4C5)( tBuN); An = Th, 1; An = U, 2; R = R′ = Me, a; R = Et, R′ = Me, b; R = R′ = Et, c), are reported. These complexes are effective precatalysts for intramolecular catalytic hydroamination/cyclization of aminoalkenes and aminoalkynes. Comparisons of structure and reactivity are drawn with previously reported trivalent organolanthanide CGC catalytic systems.
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UR - http://www.scopus.com/inward/citedby.url?scp=0345016345&partnerID=8YFLogxK
U2 - 10.1021/om034093f
DO - 10.1021/om034093f
M3 - Article
VL - 22
SP - 4836
EP - 4838
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 24
ER -