Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination

Bryan D. Stubbert; Charlotte L. Stern; Tobin J. Marks

doi:10.1021/om034093f

Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination

Bryan D. Stubbert, Charlotte L. Stern, Tobin J. Marks

Northwestern University

Research output: Contribution to journal › Article

107 Citations (Scopus)

Abstract

The synthesis, characterization, and reactivity of a series of organoactinide constrained-geometry complexes, (CGC)An(NRR′)₂ (CGC = Me₂Si(η⁵-Me₄C₅)( ^tBuN); An = Th, 1; An = U, 2; R = R′ = Me, a; R = Et, R′ = Me, b; R = R′ = Et, c), are reported. These complexes are effective precatalysts for intramolecular catalytic hydroamination/cyclization of aminoalkenes and aminoalkynes. Comparisons of structure and reactivity are drawn with previously reported trivalent organolanthanide CGC catalytic systems.

Original language	English
Pages (from-to)	4836-4838
Number of pages	3
Journal	Organometallics
Volume	22
Issue number	24
DOIs	https://doi.org/10.1021/om034093f
Publication status	Published - Nov 24 2003

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ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

Cite this

Stubbert, B. D., Stern, C. L., & Marks, T. J. (2003). Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination. Organometallics, 22(24), 4836-4838. https://doi.org/10.1021/om034093f

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10.1021/om034093f