Abstract
The synthesis, characterization, and reactivity of a series of organoactinide constrained-geometry complexes, (CGC)An(NRR′)2 (CGC = Me2Si(η5-Me4C5)( tBuN); An = Th, 1; An = U, 2; R = R′ = Me, a; R = Et, R′ = Me, b; R = R′ = Et, c), are reported. These complexes are effective precatalysts for intramolecular catalytic hydroamination/cyclization of aminoalkenes and aminoalkynes. Comparisons of structure and reactivity are drawn with previously reported trivalent organolanthanide CGC catalytic systems.
| Original language | English |
|---|---|
| Pages (from-to) | 4836-4838 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 22 |
| Issue number | 24 |
| DOIs | |
| Publication status | Published - Nov 24 2003 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry
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Stubbert, B. D., Stern, C. L., & Marks, T. J. (2003). Synthesis and Catalytic Characteristics of Novel Constrained-Geometry Organoactinide Catalysts. The First Example of Actiniae-Mediated Intramolecular Hydroamination. Organometallics, 22(24), 4836-4838. https://doi.org/10.1021/om034093f