Abstract
The synthesis of the new bis[2-(diphenylphosphino)ethyl](hydroxymethyl)phosphine tridentate ligand LCH2OH/Ph is reported. The ligand reacts with [Pd(Cl)2(PhCN)2] to form [Pd(LCH2OH/Ph)Cl]Cl. Exchange of the chloride ions for triflate (OTf-) using AgOTf yielded pure [Pd(LCH2OH/Ph)OTf]OTf. In addition to spectral characterization, the free ligand, LCH2OH/Ph, and the PdII complex, [Pd(LCH2OH/Ph)OTf]OTf, were structurally characterized. The synthesis of the Triphos ligand derivative LCH2OH/Ph is reported, along with the corresponding PdII complex. In addition to spectral characterization of the free ligand and PdII complex, structural characterization is reported for [Pd(LCH2OH/Ph)OTf]OTf.
Original language | English |
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Pages (from-to) | 5781-5785 |
Number of pages | 5 |
Journal | European Journal of Inorganic Chemistry |
Volume | 2015 |
Issue number | 35 |
DOIs | |
Publication status | Published - Dec 1 2015 |
Keywords
- Crystallography
- Electrochemistry
- P ligands
- Palladium
- Tridentate ligands
ASJC Scopus subject areas
- Inorganic Chemistry