Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]

Bruce Finkel; Long Pan; Xiaoying Huang; Jing Li

doi:10.1016/j.crci.2005.04.006

Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H₂ddc = 1,10-decanedicarboxylic acid]

Bruce Finkel, Long Pan, Xiaoying Huang, Jing Li

Rutgers University

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H₂ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C₂₄H₃₂N₂CuO₄ crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å³ and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

Original language	English
Pages (from-to)	1670-1675
Number of pages	6
Journal	Comptes Rendus Chimie
Volume	8
Issue number	9-10 SPEC. ISS.
DOIs	https://doi.org/10.1016/j.crci.2005.04.006
Publication status	Published - Sep 2005

Keywords

2D coordination polymer
Copper
Flexible ligand

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

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@article{2df120ee2a6e4769a442f94788616015,

title = "Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]",

abstract = "A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P{\=1}, a = 7.944(3) {\AA}, b = 8.714(3) {\AA}, c = 9.366(3) {\AA}, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) {\AA}3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.",

keywords = "2D coordination polymer, Copper, Flexible ligand",

author = "Bruce Finkel and Long Pan and Xiaoying Huang and Jing Li",

note = "Funding Information: We gratefully acknowledge support from the National Science Foundation (DMR-0094872 and 0422932) and partial support by Rutgers University.",

year = "2005",

month = sep,

doi = "10.1016/j.crci.2005.04.006",

language = "English",

volume = "8",

pages = "1670--1675",

journal = "Comptes Rendus Chimie",

issn = "1631-0748",

publisher = "Elsevier Masson",

number = "9-10 SPEC. ISS.",

}

TY - JOUR

T1 - Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]

AU - Finkel, Bruce

AU - Pan, Long

AU - Huang, Xiaoying

AU - Li, Jing

N1 - Funding Information: We gratefully acknowledge support from the National Science Foundation (DMR-0094872 and 0422932) and partial support by Rutgers University.

PY - 2005/9

Y1 - 2005/9

N2 - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

AB - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

KW - 2D coordination polymer

KW - Copper

KW - Flexible ligand

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