Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]

Bruce Finkel, Long Pan, Xiaoying Huang, Jing Li

Research output: Contribution to journal › Article

2 Citations (Scopus)

Abstract

A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

Original languageEnglish
Pages (from-to)1670-1675
Number of pages6
JournalComptes Rendus Chimie
Volume8
Issue number9-10 SPEC. ISS.
DOIs
Publication statusPublished - Sep 2005

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Ethane
Copper
Nitrates
Nitrogen
Acids
Temperature
triethylamine
copper(II) nitrate
dodecanedioic acid

Keywords

  • 2D coordination polymer
  • Copper
  • Flexible ligand

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. / Finkel, Bruce; Pan, Long; Huang, Xiaoying; Li, Jing.

In: Comptes Rendus Chimie, Vol. 8, No. 9-10 SPEC. ISS., 09.2005, p. 1670-1675.

Research output: Contribution to journal › Article

Finkel, B, Pan, L, Huang, X & Li, J 2005, 'Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]', Comptes Rendus Chimie, vol. 8, no. 9-10 SPEC. ISS., pp. 1670-1675. https://doi.org/10.1016/j.crci.2005.04.006
Finkel B, Pan L, Huang X, Li J. Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. Comptes Rendus Chimie. 2005 Sep;8(9-10 SPEC. ISS.):1670-1675. https://doi.org/10.1016/j.crci.2005.04.006
Finkel, Bruce ; Pan, Long ; Huang, Xiaoying ; Li, Jing. / Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. In: Comptes Rendus Chimie. 2005 ; Vol. 8, No. 9-10 SPEC. ISS. pp. 1670-1675.
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abstract = "A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) {\AA}, b = 8.714(3) {\AA}, c = 9.366(3) {\AA}, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) {\AA}3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.",
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N2 - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

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