Abstract
A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.
| Original language | English |
|---|---|
| Pages (from-to) | 1670-1675 |
| Number of pages | 6 |
| Journal | Comptes Rendus Chimie |
| Volume | 8 |
| Issue number | 9-10 SPEC. ISS. |
| DOIs | |
| Publication status | Published - Sep 2005 |
Fingerprint
Keywords
- 2D coordination polymer
- Copper
- Flexible ligand
ASJC Scopus subject areas
- Chemical Engineering(all)
- Chemistry(all)
Cite this
Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. / Finkel, Bruce; Pan, Long; Huang, Xiaoying; Li, Jing.
In: Comptes Rendus Chimie, Vol. 8, No. 9-10 SPEC. ISS., 09.2005, p. 1670-1675.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]
AU - Finkel, Bruce
AU - Pan, Long
AU - Huang, Xiaoying
AU - Li, Jing
PY - 2005/9
Y1 - 2005/9
N2 - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.
AB - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.
KW - 2D coordination polymer
KW - Copper
KW - Flexible ligand
UR - http://www.scopus.com/inward/record.url?scp=26944481127&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=26944481127&partnerID=8YFLogxK
U2 - 10.1016/j.crci.2005.04.006
DO - 10.1016/j.crci.2005.04.006
M3 - Article
AN - SCOPUS:26944481127
VL - 8
SP - 1670
EP - 1675
JO - Comptes Rendus Chimie
JF - Comptes Rendus Chimie
SN - 1631-0748
IS - 9-10 SPEC. ISS.
ER -