Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]

Bruce Finkel, Long Pan, Xiaoying Huang, Jing Li

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

Original languageEnglish
Pages (from-to)1670-1675
Number of pages6
JournalComptes Rendus Chimie
Volume8
Issue number9-10 SPEC. ISS.
DOIs
Publication statusPublished - Sep 2005

Fingerprint

Ethane
Copper
Nitrates
Nitrogen
Acids
Temperature
triethylamine
copper(II) nitrate
dodecanedioic acid

Keywords

  • 2D coordination polymer
  • Copper
  • Flexible ligand

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)

Cite this

Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. / Finkel, Bruce; Pan, Long; Huang, Xiaoying; Li, Jing.

In: Comptes Rendus Chimie, Vol. 8, No. 9-10 SPEC. ISS., 09.2005, p. 1670-1675.

Research output: Contribution to journalArticle

Finkel, Bruce ; Pan, Long ; Huang, Xiaoying ; Li, Jing. / Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]. In: Comptes Rendus Chimie. 2005 ; Vol. 8, No. 9-10 SPEC. ISS. pp. 1670-1675.
@article{2df120ee2a6e4769a442f94788616015,
title = "Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]",
abstract = "A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) {\AA}, b = 8.714(3) {\AA}, c = 9.366(3) {\AA}, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) {\AA}3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.",
keywords = "2D coordination polymer, Copper, Flexible ligand",
author = "Bruce Finkel and Long Pan and Xiaoying Huang and Jing Li",
year = "2005",
month = "9",
doi = "10.1016/j.crci.2005.04.006",
language = "English",
volume = "8",
pages = "1670--1675",
journal = "Comptes Rendus Chimie",
issn = "1631-0748",
publisher = "Elsevier Masson",
number = "9-10 SPEC. ISS.",

}

TY - JOUR

T1 - Synthesis and characterization of Cu(bpe)(ddc) [bpe = 1,2-bis(4-pyridyl)ethane, H2ddc = 1,10-decanedicarboxylic acid]

AU - Finkel, Bruce

AU - Pan, Long

AU - Huang, Xiaoying

AU - Li, Jing

PY - 2005/9

Y1 - 2005/9

N2 - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

AB - A new 2D structure, Cu(bpe)(ddc) was synthesized by a reaction of hydrated cupric nitrate, 1,2-bis(4-pyridyl)ethane (bpe), 1,10-decanedicarboxylic acid (H2ddc) and triethylamine (tea) via a room temperature diffusion method. The compound with chemical formula C24H32N2CuO4 crystallizes in triclinic space group P1̄, a = 7.944(3) Å, b = 8.714(3) Å, c = 9.366(3) Å, α = 64.55(3)°, β = 86.72(2)°, γ = 73.74(3)°, V = 560.5(3) Å3 and Z = 1. Within the structure, each copper forms four equatorial bonds with two ddc and two axial bonds with two bpe to give rise to a distorted octahedron. The Cu-ddc connections generate a 1D zigzag chain. The chains are further connected via bpe nitrogen at Cu axial positions to result in a 2D layered structure.

KW - 2D coordination polymer

KW - Copper

KW - Flexible ligand

UR - http://www.scopus.com/inward/record.url?scp=26944481127&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=26944481127&partnerID=8YFLogxK

U2 - 10.1016/j.crci.2005.04.006

DO - 10.1016/j.crci.2005.04.006

M3 - Article

AN - SCOPUS:26944481127

VL - 8

SP - 1670

EP - 1675

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

SN - 1631-0748

IS - 9-10 SPEC. ISS.

ER -