Synthesis and characterization of ferrite materials for thermochemical CO2 splitting using concentrated solar energy

Andrea Ambrosini; Eric N. Coker; Mark A. Rodriguez; Stephanie Livers; Lindsey R. Evans; James E. Miller; Ellen B. Stechel

doi:10.1021/bk-2010-1056.ch001

Synthesis and characterization of ferrite materials for thermochemical CO₂ splitting using concentrated solar energy

Andrea Ambrosini, Eric N. Coker, Mark A. Rodriguez, Stephanie Livers, Lindsey R. Evans, James E. Miller, Ellen B. Stechel

Arizona State University

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

14 Citations (Scopus)

Abstract

The Sunshine to Petrol effort at Sandia aims to convert carbon dioxide and water to precursors for liquid hydrocarbon fuels using concentrated solar power. Significant advances have been made in the field of solar thermochemical CO₂-splitting technologies utilizing yttria-stabilized zirconia (YSZ)-supported ferrite composites. Conceptually, such materials work via the basic redox reactions: Fe₃O₄→ ₃FeO + 0.5O₂ (Thermal reduction, >1350°C) and ₃FeO + CO₂→ Fe₃O₄ + CO (CO₂-splitting oxidation, <1200°C). There has been limited fundamental characterization of the ferrite-based materials at the high temperatures and conditions present in these cycles. A systematic study of these composites is underway in an effort to begin to elucidate microstructure, structure-property relationships, and the role of the support on redox behavior under high-temperature reducing and oxidizing environments. In this paper the synthesis, structural characterization (including scanning electron microscopy and room temperature and in-situ x-ray diffraction), and thermogravimetric analysis of YSZ-supported ferrites will be reported.

Original language	English
Title of host publication	Advances in CO2 Conversion and Utilization
Publisher	American Chemical Society
Pages	1-13
Number of pages	13
ISBN (Print)	9780841225961
DOIs	https://doi.org/10.1021/bk-2010-1056.ch001
Publication status	Published - Dec 3 2010

Publication series

Name	ACS Symposium Series
Volume	1056
ISSN (Print)	0097-6156
ISSN (Electronic)	1947-5918

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)

Access to Document

10.1021/bk-2010-1056.ch001

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Ambrosini, A., Coker, E. N., Rodriguez, M. A., Livers, S., Evans, L. R., Miller, J. E., & Stechel, E. B. (2010). Synthesis and characterization of ferrite materials for thermochemical CO₂ splitting using concentrated solar energy. In Advances in CO2 Conversion and Utilization (pp. 1-13). (ACS Symposium Series; Vol. 1056). American Chemical Society. https://doi.org/10.1021/bk-2010-1056.ch001

Synthesis and characterization of ferrite materials for thermochemical CO₂ splitting using concentrated solar energy. / Ambrosini, Andrea; Coker, Eric N.; Rodriguez, Mark A.; Livers, Stephanie; Evans, Lindsey R.; Miller, James E.; Stechel, Ellen B.

Advances in CO2 Conversion and Utilization. American Chemical Society, 2010. p. 1-13 (ACS Symposium Series; Vol. 1056).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution

Ambrosini, A, Coker, EN, Rodriguez, MA, Livers, S, Evans, LR, Miller, JE & Stechel, EB 2010, Synthesis and characterization of ferrite materials for thermochemical CO₂ splitting using concentrated solar energy. in Advances in CO2 Conversion and Utilization. ACS Symposium Series, vol. 1056, American Chemical Society, pp. 1-13. https://doi.org/10.1021/bk-2010-1056.ch001

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