Synthesis and characterization of indium thiolates

structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]

Wakgari Hirpo, Anthony C. Sutorik, Sandeep Dhingra, Mercouri G Kanatzidis

Research output: Contribution to journal › Article

13 Citations (Scopus)

Abstract

Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

Original languageEnglish
Pages (from-to)2797-2800
Number of pages4
JournalPolyhedron
Volume13
Issue number19
DOIs
Publication statusPublished - 1994

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Indium
Methanol
indium
X-Rays
Crystals
synthesis
crystals
methyl alcohol
X rays
x rays

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis and characterization of indium thiolates : structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]. / Hirpo, Wakgari; Sutorik, Anthony C.; Dhingra, Sandeep; Kanatzidis, Mercouri G.

In: Polyhedron, Vol. 13, No. 19, 1994, p. 2797-2800.

Research output: Contribution to journal › Article

Hirpo, W, Sutorik, AC, Dhingra, S & Kanatzidis, MG 1994, 'Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]', Polyhedron, vol. 13, no. 19, pp. 2797-2800. https://doi.org/10.1016/S0277-5387(00)83439-7
Hirpo W, Sutorik AC, Dhingra S, Kanatzidis MG. Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]. Polyhedron. 1994;13(19):2797-2800. https://doi.org/10.1016/S0277-5387(00)83439-7
Hirpo, Wakgari ; Sutorik, Anthony C. ; Dhingra, Sandeep ; Kanatzidis, Mercouri G. / Synthesis and characterization of indium thiolates : structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]. In: Polyhedron. 1994 ; Vol. 13, No. 19. pp. 2797-2800.
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abstract = "Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.",
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AU - Dhingra, Sandeep

AU - Kanatzidis, Mercouri G

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AB - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

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