Abstract
Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
| Original language | English |
|---|---|
| Pages (from-to) | 2797-2800 |
| Number of pages | 4 |
| Journal | Polyhedron |
| Volume | 13 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 1994 |
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ASJC Scopus subject areas
- Biochemistry
- Inorganic Chemistry
- Physical and Theoretical Chemistry
- Materials Chemistry
Cite this
Synthesis and characterization of indium thiolates : structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]. / Hirpo, Wakgari; Sutorik, Anthony C.; Dhingra, Sandeep; Kanatzidis, Mercouri G.
In: Polyhedron, Vol. 13, No. 19, 1994, p. 2797-2800.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and characterization of indium thiolates
T2 - structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]
AU - Hirpo, Wakgari
AU - Sutorik, Anthony C.
AU - Dhingra, Sandeep
AU - Kanatzidis, Mercouri G
PY - 1994
Y1 - 1994
N2 - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
AB - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
UR - http://www.scopus.com/inward/record.url?scp=0011672305&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0011672305&partnerID=8YFLogxK
U2 - 10.1016/S0277-5387(00)83439-7
DO - 10.1016/S0277-5387(00)83439-7
M3 - Article
AN - SCOPUS:0011672305
VL - 13
SP - 2797
EP - 2800
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 19
ER -