Abstract
Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
| Original language | English |
|---|---|
| Pages (from-to) | 2797-2800 |
| Number of pages | 4 |
| Journal | Polyhedron |
| Volume | 13 |
| Issue number | 19 |
| DOIs | |
| Publication status | Published - 1994 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry
Fingerprint Dive into the research topics of 'Synthesis and characterization of indium thiolates: structures of [Ph<sub>4</sub>P][In(SBu<sup>t</sup>)<sub>4</sub>·CH<sub>3</sub>OH and [Ph<sub>4</sub>P][In(SCH<sub>2</sub>CH<sub>2</sub>S)<sub>2</sub>]'. Together they form a unique fingerprint.
Cite this
Hirpo, W., Sutorik, A. C., Dhingra, S., & Kanatzidis, M. G. (1994). Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]. Polyhedron, 13(19), 2797-2800. https://doi.org/10.1016/S0277-5387(00)83439-7