Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]

Wakgari Hirpo; Anthony C. Sutorik; Sandeep Dhingra; Mercouri G. Kanatzidis

doi:10.1016/S0277-5387(00)83439-7

Synthesis and characterization of indium thiolates: structures of [Ph₄P][In(SBu^t)₄·CH₃OH and [Ph₄P][In(SCH₂CH₂S)₂]

Wakgari Hirpo, Anthony C. Sutorik, Sandeep Dhingra, Mercouri G. Kanatzidis

Northwestern University

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Reaction of InCl₃ with four equivalents of KSBu^t in the presence of Ph₄PCl gave the monomeric complex [Ph₄P][In(SBu^t)₄·CH₃OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl₃ with NaSCH₂CH₂SNa and Ph₄PBr gave [Ph₄P][In(SCH₂CH₂S)₂] (2), which readily crystallized from CH₃CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

Original language	English
Pages (from-to)	2797-2800
Number of pages	4
Journal	Polyhedron
Volume	13
Issue number	19
DOIs	https://doi.org/10.1016/S0277-5387(00)83439-7
Publication status	Published - 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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@article{67997547a3964d758a0e38f80e7bd8b9,

title = "Synthesis and characterization of indium thiolates: structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]",

abstract = "Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.",

author = "Wakgari Hirpo and Sutorik, {Anthony C.} and Sandeep Dhingra and Kanatzidis, {Mercouri G.}",

note = "Funding Information: Acknowledgements-Financials upport from NASA is gratefullya cknowledgedM. .G.K. is an A. P. Sloan Foundation Fellow (1991-93)a nd a Camille and Henry Drey-fuss Teacher-Scholar( 1993-95).P artial support from the Donors of the Petroleum ResearchF und is also acknowledgedT. he X-ray instrumentationu sed in this work wasp urchasedin part with funds from NSF Grant CHE-8908088.W e also thank the Center for Electron Optics at Michigan StateU niversity for use of the electron microscopyf acilities.",

year = "1994",

doi = "10.1016/S0277-5387(00)83439-7",

language = "English",

volume = "13",

pages = "2797--2800",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Limited",

number = "19",

}

TY - JOUR

T1 - Synthesis and characterization of indium thiolates

T2 - structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]

AU - Hirpo, Wakgari

AU - Sutorik, Anthony C.

AU - Dhingra, Sandeep

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: Acknowledgements-Financials upport from NASA is gratefullya cknowledgedM. .G.K. is an A. P. Sloan Foundation Fellow (1991-93)a nd a Camille and Henry Drey-fuss Teacher-Scholar( 1993-95).P artial support from the Donors of the Petroleum ResearchF und is also acknowledgedT. he X-ray instrumentationu sed in this work wasp urchasedin part with funds from NSF Grant CHE-8908088.W e also thank the Center for Electron Optics at Michigan StateU niversity for use of the electron microscopyf acilities.

PY - 1994

Y1 - 1994

N2 - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

AB - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.

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M3 - Article

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VL - 13

SP - 2797

EP - 2800

JO - Polyhedron

JF - Polyhedron

SN - 0277-5387

IS - 19

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