TY - JOUR
T1 - Synthesis and characterization of indium thiolates
T2 - structures of [Ph4P][In(SBut)4·CH3OH and [Ph4P][In(SCH2CH2S)2]
AU - Hirpo, Wakgari
AU - Sutorik, Anthony C.
AU - Dhingra, Sandeep
AU - Kanatzidis, Mercouri G.
N1 - Funding Information:
Acknowledgements-Financials upport from NASA is gratefullya cknowledgedM. .G.K. is an A. P. Sloan Foundation Fellow (1991-93)a nd a Camille and Henry Drey-fuss Teacher-Scholar( 1993-95).P artial support from the Donors of the Petroleum ResearchF und is also acknowledgedT. he X-ray instrumentationu sed in this work wasp urchasedin part with funds from NSF Grant CHE-8908088.W e also thank the Center for Electron Optics at Michigan StateU niversity for use of the electron microscopyf acilities.
PY - 1994
Y1 - 1994
N2 - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
AB - Reaction of InCl3 with four equivalents of KSBut in the presence of Ph4PCl gave the monomeric complex [Ph4P][In(SBut)4·CH3OH (1) which crystallized from methanol as colourless hexagonal shaped crystals. Reaction of InCl3 with NaSCH2CH2SNa and Ph4PBr gave [Ph4P][In(SCH2CH2S)2] (2), which readily crystallized from CH3CN as colourless crystals. Both 1 and 2 were shown by X-ray structures to have tetrahedral coordination of indium.
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U2 - 10.1016/S0277-5387(00)83439-7
DO - 10.1016/S0277-5387(00)83439-7
M3 - Article
AN - SCOPUS:0011672305
VL - 13
SP - 2797
EP - 2800
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
IS - 19
ER -