Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.
|Number of pages||4|
|Journal||Angewandte Chemie - International Edition|
|Publication status||Published - Sep 1 2000|
- Zeolite analogues
ASJC Scopus subject areas