Synthesis and characterization of iron silasesquioxane phosphane complexes

Fuchen Liu, Kevin D. John, Brian L. Scott, R. Tom Baker, Kevin C. Ott, William Tumas

Research output: Contribution to journalArticle

33 Citations (Scopus)

Abstract

Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.

Original languageEnglish
Pages (from-to)3127-3130
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number17
DOIs
Publication statusPublished - Sep 1 2000

Fingerprint

phosphine
Iron
Benzene
Dimers
Single crystals
X rays

Keywords

  • Iron
  • Silasesquioxanes
  • Silicates
  • Zeolite analogues

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and characterization of iron silasesquioxane phosphane complexes. / Liu, Fuchen; John, Kevin D.; Scott, Brian L.; Baker, R. Tom; Ott, Kevin C.; Tumas, William.

In: Angewandte Chemie - International Edition, Vol. 39, No. 17, 01.09.2000, p. 3127-3130.

Research output: Contribution to journalArticle

Liu, Fuchen ; John, Kevin D. ; Scott, Brian L. ; Baker, R. Tom ; Ott, Kevin C. ; Tumas, William. / Synthesis and characterization of iron silasesquioxane phosphane complexes. In: Angewandte Chemie - International Edition. 2000 ; Vol. 39, No. 17. pp. 3127-3130.
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