Synthesis and characterization of iron silasesquioxane phosphane complexes

Fuchen Liu, Kevin D. John, Brian L. Scott, R. Tom Baker, Kevin C. Ott, William Tumas

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33 Citations (Scopus)

Abstract

Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.

Original languageEnglish
Pages (from-to)3127-3130
Number of pages4
JournalAngewandte Chemie - International Edition
Volume39
Issue number17
DOIs
Publication statusPublished - Sep 1 2000

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Keywords

  • Iron
  • Silasesquioxanes
  • Silicates
  • Zeolite analogues

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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