Synthesis and characterization of iron silasesquioxane phosphane complexes

Fuchen Liu; Kevin D. John; Brian L. Scott; R. Tom Baker; Kevin C. Ott; William Tumas

doi:10.1002/1521-3773(20000901)39:17<3127::AID-ANIE3127>3.0.CO;2-F

Synthesis and characterization of iron silasesquioxane phosphane complexes

Fuchen Liu, Kevin D. John, Brian L. Scott, R. Tom Baker, Kevin C. Ott, William Tumas

National Renewable Energy Laboratory

Research output: Contribution to journal › Article › peer-review

36 Citations (Scopus)

Abstract

Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.

Original language	English
Pages (from-to)	3127-3130
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	39
Issue number	17
DOIs	https://doi.org/10.1002/1521-3773(20000901)39:17<3127::AID-ANIE3127>3.0.CO;2-F
Publication status	Published - Sep 1 2000

Keywords

Iron
Silasesquioxanes
Silicates
Zeolite analogues

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/1521-3773(20000901)39:17<3127::AID-ANIE3127>3.0.CO;2-F

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AU - Liu, Fuchen

AU - John, Kevin D.

AU - Scott, Brian L.

AU - Baker, R. Tom

AU - Ott, Kevin C.

AU - Tumas, William

PY - 2000/9/1

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AB - Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.

KW - Iron

KW - Silasesquioxanes

KW - Silicates

KW - Zeolite analogues

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