Abstract
Iron centers in highly siliceous environments have been isolated by the reaction of incompletely condensed polyhedral silasesquioxanes with iron phosphane complexes in benzene. Among the new compounds is the oxo-bridged dianionic dimer 1. Single-crystal X-ray structures and preliminary reactivity studies are described.
| Original language | English |
|---|---|
| Pages (from-to) | 3127-3130 |
| Number of pages | 4 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 39 |
| Issue number | 17 |
| DOIs | |
| Publication status | Published - Sep 1 2000 |
Keywords
- Iron
- Silasesquioxanes
- Silicates
- Zeolite analogues
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
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Liu, F., John, K. D., Scott, B. L., Baker, R. T., Ott, K. C., & Tumas, W. (2000). Synthesis and characterization of iron silasesquioxane phosphane complexes. Angewandte Chemie - International Edition, 39(17), 3127-3130. https://doi.org/10.1002/1521-3773(20000901)39:17<3127::AID-ANIE3127>3.0.CO;2-F