Abstract
Square-planar palladium complexes containing tridentate ligands with PXP (X = C, N, O, S, and As) donor sets have been prepared. For (Pd(POP-R)(CH3CN)2)(BF4)2 complexes (where POP-R is bis((diethylphosphine)ethyl)ether), bis((diphenylphosphino)ethyl)ether, or Bis((dicyclohexylphosphino)ethyl)ether), the POP-R ligands function as bidentate ligands. For all other complexes, the PXP ligands function as tridentate ligands. The dependence of the catalytic current on CO2 and acid concentrations is consistent with the formation of a hydroxycarbonyl intermediate which decomposes in the presence of acid to form hydrogen as the catalytic product.
| Original language | English |
|---|---|
| Pages (from-to) | 4844-4855 |
| Number of pages | 12 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 12 |
| Publication status | Published - Dec 1994 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Synthesis and characterization of palladium complexes containing tridentate ligands with PXP (X = C, N, O, S, As) donor sets and their evaluation as electrochemical CO2 reduction catalysts. / Steffey, B. D.; Miedaner, A.; Maciejewski-Farmer, M. L.; Bernatis, P. R.; Herring, A. M.; Allured, V. S.; Carperos, V.; DuBois, Daniel L.
In: Organometallics, Vol. 13, No. 12, 12.1994, p. 4844-4855.Research output: Contribution to journal › Article
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TY - JOUR
T1 - Synthesis and characterization of palladium complexes containing tridentate ligands with PXP (X = C, N, O, S, As) donor sets and their evaluation as electrochemical CO2 reduction catalysts
AU - Steffey, B. D.
AU - Miedaner, A.
AU - Maciejewski-Farmer, M. L.
AU - Bernatis, P. R.
AU - Herring, A. M.
AU - Allured, V. S.
AU - Carperos, V.
AU - DuBois, Daniel L
PY - 1994/12
Y1 - 1994/12
N2 - Square-planar palladium complexes containing tridentate ligands with PXP (X = C, N, O, S, and As) donor sets have been prepared. For (Pd(POP-R)(CH3CN)2)(BF4)2 complexes (where POP-R is bis((diethylphosphine)ethyl)ether), bis((diphenylphosphino)ethyl)ether, or Bis((dicyclohexylphosphino)ethyl)ether), the POP-R ligands function as bidentate ligands. For all other complexes, the PXP ligands function as tridentate ligands. The dependence of the catalytic current on CO2 and acid concentrations is consistent with the formation of a hydroxycarbonyl intermediate which decomposes in the presence of acid to form hydrogen as the catalytic product.
AB - Square-planar palladium complexes containing tridentate ligands with PXP (X = C, N, O, S, and As) donor sets have been prepared. For (Pd(POP-R)(CH3CN)2)(BF4)2 complexes (where POP-R is bis((diethylphosphine)ethyl)ether), bis((diphenylphosphino)ethyl)ether, or Bis((dicyclohexylphosphino)ethyl)ether), the POP-R ligands function as bidentate ligands. For all other complexes, the PXP ligands function as tridentate ligands. The dependence of the catalytic current on CO2 and acid concentrations is consistent with the formation of a hydroxycarbonyl intermediate which decomposes in the presence of acid to form hydrogen as the catalytic product.
UR - http://www.scopus.com/inward/record.url?scp=0028748541&partnerID=8YFLogxK
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M3 - Article
VL - 13
SP - 4844
EP - 4855
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 12
ER -