Synthesis and characterization of size-controlled vanadium dioxide nanocrystals in a fused silica matrix

R. Lopez, L. A. Boatner, T. E. Haynes, Leonard C Feldman, R. F. Haglund

Research output: Contribution to journalArticle

129 Citations (Scopus)

Abstract

Vanadium dioxide single-crystal precipitates with controlled particle sizes were produced in an amorphous, fused SiO 2 host by the stoichiometric coimplantation of vanadium and oxygen ions and subsequent thermal processing. The effects of the vanadium dioxide nanocrystal size, nanocrystal morphology, and particle/host interactions on the VO 2 semiconductor-to-metal phase transition were characterized. VO 2 nanoparticles embedded in amorphous SiO 2 exhibit a sharp phase transition with a hysteresis that is up to 50°C in width - one of the largest values ever reported for this transition. The relative decrease in the optical transmission in the near-infrared region in going from the semiconducting to the metallic phase of VO 2 ranges from 20% to 35%. Both the hysteresis width and the transition temperature are correlated with the size of the precipitates. Doping the embedded VO 2 particles with ions such as titanium alters the characteristics of the phase transition, pointing the way to control the hysteresis behavior over a wide range of values and providing insight into the operative physical mechanisms.

Original languageEnglish
Pages (from-to)4031-4036
Number of pages6
JournalJournal of Applied Physics
Volume92
Issue number7
DOIs
Publication statusPublished - Oct 1 2002

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dioxides
vanadium
nanocrystals
silicon dioxide
hysteresis
synthesis
matrices
precipitates
particle interactions
oxygen ions
ions
titanium
transition temperature
nanoparticles
single crystals
metals

ASJC Scopus subject areas

  • Physics and Astronomy(all)

Cite this

Synthesis and characterization of size-controlled vanadium dioxide nanocrystals in a fused silica matrix. / Lopez, R.; Boatner, L. A.; Haynes, T. E.; Feldman, Leonard C; Haglund, R. F.

In: Journal of Applied Physics, Vol. 92, No. 7, 01.10.2002, p. 4031-4036.

Research output: Contribution to journalArticle

Lopez, R. ; Boatner, L. A. ; Haynes, T. E. ; Feldman, Leonard C ; Haglund, R. F. / Synthesis and characterization of size-controlled vanadium dioxide nanocrystals in a fused silica matrix. In: Journal of Applied Physics. 2002 ; Vol. 92, No. 7. pp. 4031-4036.
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