Abstract
Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (CuII, MgII, and MnII salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.
Original language | English |
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Pages (from-to) | 1292-1296 |
Number of pages | 5 |
Journal | Chemistry of Materials |
Volume | 24 |
Issue number | 7 |
DOIs | |
Publication status | Published - Apr 10 2012 |
Keywords
- Hydrogen storage
- Metal catecholates
- Porous organic polymers
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
- Materials Chemistry