Abstract
Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m 2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (Cu II, Mg II, and Mn II salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.
| Original language | English |
|---|---|
| Pages (from-to) | 1292-1296 |
| Number of pages | 5 |
| Journal | Chemistry of Materials |
| Volume | 24 |
| Issue number | 7 |
| DOIs | |
| Publication status | Published - 2012 |
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Keywords
- Hydrogen storage
- Metal catecholates
- Porous organic polymers
ASJC Scopus subject areas
- Materials Chemistry
- Chemical Engineering(all)
- Chemistry(all)
Cite this
Synthesis and metalation of catechol-functionalized porous organic polymers. / Weston, Mitchell H.; Farha, Omar K.; Hauser, Brad G.; Hupp, Joseph T.; Nguyen, Sonbinh T.
In: Chemistry of Materials, Vol. 24, No. 7, 2012, p. 1292-1296.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and metalation of catechol-functionalized porous organic polymers
AU - Weston, Mitchell H.
AU - Farha, Omar K.
AU - Hauser, Brad G.
AU - Hupp, Joseph T.
AU - Nguyen, Sonbinh T.
PY - 2012
Y1 - 2012
N2 - Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m 2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (Cu II, Mg II, and Mn II salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.
AB - Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m 2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (Cu II, Mg II, and Mn II salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.
KW - Hydrogen storage
KW - Metal catecholates
KW - Porous organic polymers
UR - http://www.scopus.com/inward/record.url?scp=84861537648&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=84861537648&partnerID=8YFLogxK
U2 - 10.1021/cm2034646
DO - 10.1021/cm2034646
M3 - Article
AN - SCOPUS:84861537648
VL - 24
SP - 1292
EP - 1296
JO - Chemistry of Materials
JF - Chemistry of Materials
SN - 0897-4756
IS - 7
ER -