Abstract
Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m 2/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (Cu II, Mg II, and Mn II salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.
Original language | English |
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Pages (from-to) | 1292-1296 |
Number of pages | 5 |
Journal | Chemistry of Materials |
Volume | 24 |
Issue number | 7 |
DOIs | |
Publication status | Published - Jun 1 2012 |
Keywords
- Hydrogen storage
- Metal catecholates
- Porous organic polymers
ASJC Scopus subject areas
- Chemistry(all)
- Chemical Engineering(all)
- Materials Chemistry