Synthesis and metalation of catechol-functionalized porous organic polymers

Mitchell H. Weston; Omar K. Farha; Brad G. Hauser; Joseph T. Hupp; Sonbinh T. Nguyen

doi:10.1021/cm2034646

Synthesis and metalation of catechol-functionalized porous organic polymers

Mitchell H. Weston, Omar K. Farha, Brad G. Hauser, Joseph T. Hupp, Sonbinh T. Nguyen

Northwestern University

Research output: Contribution to journal › Article

82 Citations (Scopus)

Abstract

Robust catechol-functionalized porous organic polymers (POPs) with tunable porosities (560-1050 m ²/g) and degrees of functionalization were synthesized using a cobaltcatalyzed acetylene trimerization (CCAT) strategy. Post-synthesis metalation can be readily carried out with a wide range of metal precursors (Cu ^II, Mg ^II, and Mn ^II salts and complexes), resulting in metalated POPs with enhanced heat of hydrogen adsorptions compared to the starting nonmetalated materials.

Original language	English
Pages (from-to)	1292-1296
Number of pages	5
Journal	Chemistry of Materials
Volume	24
Issue number	7
DOIs	https://doi.org/10.1021/cm2034646
Publication status	Published - Jun 1 2012

Keywords

Hydrogen storage
Metal catecholates
Porous organic polymers

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Chemistry

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10.1021/cm2034646

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Weston, M. H., Farha, O. K., Hauser, B. G., Hupp, J. T., & Nguyen, S. T. (2012). Synthesis and metalation of catechol-functionalized porous organic polymers. Chemistry of Materials, 24(7), 1292-1296. https://doi.org/10.1021/cm2034646

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AU - Nguyen, Sonbinh T.

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