Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond

Todd B. Marder, Dominic M T Chan, William C. Fultz, David Milstein

Research output: Contribution to journal › Article

6 Citations (Scopus)

Abstract

Reaction of [(PMe3)3RhCl] with pent-4-ynoic acid yields the novel exocyclic methylene-substituted rhoda-lactone [(PMe 3)3ClRh-C(=CH2)CH2CH 2C(=O)O], which reacts with Me3O+BF 4- to give [(PMe3)3ClRh-C(=CH 2)CH2CH2C(OMe)=O]BF4; both complexes have been structurally characterized.

Original languageEnglish
Pages (from-to)996-998
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number15
DOIs
Publication statusPublished - 1988

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Rhodium
Alkynes
Alkylation
Lactones
Molecular Structure
Molecular structure
Hydrogen
Hydrogen bonds
Acids

ASJC Scopus subject areas

  • Molecular Medicine

Cite this

Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond. / Marder, Todd B.; Chan, Dominic M T; Fultz, William C.; Milstein, David.

In: Journal of the Chemical Society, Chemical Communications, No. 15, 1988, p. 996-998.

Research output: Contribution to journal › Article

Marder, TB, Chan, DMT, Fultz, WC & Milstein, D 1988, 'Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond', Journal of the Chemical Society, Chemical Communications, no. 15, pp. 996-998. https://doi.org/10.1039/C39880000996
Marder TB, Chan DMT, Fultz WC, Milstein D. Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond. Journal of the Chemical Society, Chemical Communications. 1988;(15):996-998. https://doi.org/10.1039/C39880000996
Marder, Todd B. ; Chan, Dominic M T ; Fultz, William C. ; Milstein, David. / Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond. In: Journal of the Chemical Society, Chemical Communications. 1988 ; No. 15. pp. 996-998.
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