Abstract
Reaction of [(PMe3)3RhCl] with pent-4-ynoic acid yields the novel exocyclic methylene-substituted rhoda-lactone [(PMe 3)3ClRh-C(=CH2)CH2CH 2C(=O)O], which reacts with Me3O+BF 4- to give [(PMe3)3ClRh-C(=CH 2)CH2CH2C(OMe)=O]BF4; both complexes have been structurally characterized.
| Original language | English |
|---|---|
| Pages (from-to) | 996-998 |
| Number of pages | 3 |
| Journal | Journal of the Chemical Society, Chemical Communications |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 1988 |
ASJC Scopus subject areas
- Molecular Medicine
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Marder, T. B., Chan, D. M. T., Fultz, W. C., & Milstein, D. (1988). Synthesis and molecular structures of a rhoda-lactone and its alkylation product; insertion of a pendant alkyne into a rhodium-hydrogen bond. Journal of the Chemical Society, Chemical Communications, (15), 996-998. https://doi.org/10.1039/C39880000996