Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

Henriette Wolpher, Magnus Borgström, Leif Hammarström, Jonas Bergquist, Villy Sundström, Stenbjörn Styring, Licheng Sun, Björn Åkermark

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown.

Original languageEnglish
Pages (from-to)989-991
Number of pages3
JournalInorganic Chemistry Communications
Volume6
Issue number8
DOIs
Publication statusPublished - Aug 1 2003

Fingerprint

Photosensitizing Agents
Photosensitizers
Ruthenium
ruthenium
Catalytic Domain
Iron
Electrochemistry
iron
synthesis
electrochemistry
Oxidation-Reduction
iron hydrogenase

Keywords

  • Biomimetic model
  • Dinuclear iron complex
  • Iron hydrogenase
  • Photosensitizer
  • Ruthenium tris-bipyridine

ASJC Scopus subject areas

  • Biochemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer. / Wolpher, Henriette; Borgström, Magnus; Hammarström, Leif; Bergquist, Jonas; Sundström, Villy; Styring, Stenbjörn; Sun, Licheng; Åkermark, Björn.

In: Inorganic Chemistry Communications, Vol. 6, No. 8, 01.08.2003, p. 989-991.

Research output: Contribution to journalArticle

Wolpher, Henriette ; Borgström, Magnus ; Hammarström, Leif ; Bergquist, Jonas ; Sundström, Villy ; Styring, Stenbjörn ; Sun, Licheng ; Åkermark, Björn. / Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer. In: Inorganic Chemistry Communications. 2003 ; Vol. 6, No. 8. pp. 989-991.
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