Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

Henriette Wolpher; Magnus Borgström; Leif Hammarström; Jonas Bergquist; Villy Sundström; Stenbjörn Styring; Licheng Sun; Björn Åkermark

doi:10.1016/S1387-7003(03)00140-0

Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer

Henriette Wolpher, Magnus Borgström, Leif Hammarström, Jonas Bergquist, Villy Sundström, Stenbjörn Styring, Licheng Sun, Björn Åkermark

Uppsala University

Research output: Contribution to journal › Article › peer-review

54 Citations (Scopus)

Abstract

A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown.

Original language	English
Pages (from-to)	989-991
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	6
Issue number	8
DOIs	https://doi.org/10.1016/S1387-7003(03)00140-0
Publication status	Published - Aug 1 2003

Keywords

Biomimetic model
Dinuclear iron complex
Iron hydrogenase
Photosensitizer
Ruthenium tris-bipyridine

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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Synthesis and properties of an iron hydrogenase active site model linked to a ruthenium tris-bipyridine photosensitizer. / Wolpher, Henriette; Borgström, Magnus; Hammarström, Leif; Bergquist, Jonas; Sundström, Villy; Styring, Stenbjörn; Sun, Licheng; Åkermark, Björn.

In: Inorganic Chemistry Communications, Vol. 6, No. 8, 01.08.2003, p. 989-991.

Research output: Contribution to journal › Article › peer-review

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abstract = "A dinuclear iron complex, related to the active site of Fe hydrogenases, has been covalently linked to a redox active ruthenium tris-bipyridine type photosensitizer. Photophysics and electrochemistry of this system are studied in solution. IR spectra of this complex together with its precursor, the dinuclear iron complex, were also shown.",

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AU - Wolpher, Henriette

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AU - Sundström, Villy

AU - Styring, Stenbjörn

AU - Sun, Licheng

AU - Åkermark, Björn

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