Abstract
The new cyclic phosphetane cis- and trans-3-tert-butyl-1-phenylphosphetane (1) was prepared by a heteroatom metallacycle transfer reaction from 3-tert-butyltitanacyclobutane and dichlorophenylphosphine. Phosphetane 1 is stable to polymerization in the presence of electrophilic initiators in solution but forms low oligomers when the neat liquid is heated (>250°C for 120 h). Phosphetane 1 was employed to form the phosphetane complex cis -dichlorobis(3-tert -butyl-1-phenylphosphetane)platinum(II), which was characterized by X-ray diffraction.
| Original language | English |
|---|---|
| Pages (from-to) | 2944-2947 |
| Number of pages | 4 |
| Journal | Organometallics |
| Volume | 11 |
| Issue number | 8 |
| Publication status | Published - 1992 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Synthesis and reactivity of cyclic phosphetanes. Oligomerization, quaternization, and complexation with platinum(II). / Tumas, William; Huang, Jean C.; Fanwick, Phillip E.; Kubiak, Clifford P.
In: Organometallics, Vol. 11, No. 8, 1992, p. 2944-2947.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and reactivity of cyclic phosphetanes. Oligomerization, quaternization, and complexation with platinum(II)
AU - Tumas, William
AU - Huang, Jean C.
AU - Fanwick, Phillip E.
AU - Kubiak, Clifford P.
PY - 1992
Y1 - 1992
N2 - The new cyclic phosphetane cis- and trans-3-tert-butyl-1-phenylphosphetane (1) was prepared by a heteroatom metallacycle transfer reaction from 3-tert-butyltitanacyclobutane and dichlorophenylphosphine. Phosphetane 1 is stable to polymerization in the presence of electrophilic initiators in solution but forms low oligomers when the neat liquid is heated (>250°C for 120 h). Phosphetane 1 was employed to form the phosphetane complex cis -dichlorobis(3-tert -butyl-1-phenylphosphetane)platinum(II), which was characterized by X-ray diffraction.
AB - The new cyclic phosphetane cis- and trans-3-tert-butyl-1-phenylphosphetane (1) was prepared by a heteroatom metallacycle transfer reaction from 3-tert-butyltitanacyclobutane and dichlorophenylphosphine. Phosphetane 1 is stable to polymerization in the presence of electrophilic initiators in solution but forms low oligomers when the neat liquid is heated (>250°C for 120 h). Phosphetane 1 was employed to form the phosphetane complex cis -dichlorobis(3-tert -butyl-1-phenylphosphetane)platinum(II), which was characterized by X-ray diffraction.
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UR - http://www.scopus.com/inward/citedby.url?scp=0001295773&partnerID=8YFLogxK
M3 - Article
VL - 11
SP - 2944
EP - 2947
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 8
ER -