Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition

Junling Lu, Jeffrey W. Elam, Peter C Stair

Research output: Contribution to journalArticle

134 Citations (Scopus)

Abstract

Supported metal nanoparticles are among the most important cata-lysts for many practical reactions, including petroleum refining, automobile exhaust treatment, and Fischer-Tropsch synthesis. The catalytic performance strongly depends on the size, composition, and structure of the metal nanoparticles, as well as the underlying support. Scientists have used conventional synthesis methods including impregnation, ion exchange, and deposition-precipitation to control and tune these factors, to establish structure-performance relationships, and to develop better catalysts. Meanwhile, chemists have improved the stability of metal nanoparticles against sintering by the application of protective layers, such as polymers and oxides that encapsulate the metal particle. This often leads to decreased catalytic activity due to a lack of precise control over the thickness of the protective layer.A promising method of catalyst synthesis is atomic layer deposition (ALD). ALD is a variation on chemical vapor deposition in which metals, oxides, and other materials are deposited on surfaces by a sequence of self-limiting reactions. The self-limiting character of these reactions makes it possible to achieve uniform deposits on high-surface-area porous solids. Therefore, design and synthesis of advanced catalysts on the nanoscale becomes possible through precise control over the structure and composition of the underlying support, the catalytic active sites, and the protective layer. In this Account, we describe our advances in the synthesis and stabilization of supported metal catalysts by ALD. After a short introduction to the technique of ALD, we show several strategies for metal catalyst synthesis by ALD that take advantage of its self-limiting feature. Monometallic and bimetallic catalysts with precise control over the metal particle size, composition, and structure were achieved by combining ALD sequences, surface treatments, and deposition temperature control.Next, we describe ALD oxide overcoats applied with atomically precise thickness control that stabilize metal catalysts while preserving their catalytic function. We also discuss strategies for generation and control over the porosity of the overcoats that allow the embedded metal particles to remain accessible by reactants, and the details for ALD alumina overcoats on metal catalysts. Moreover, using methanol decomposition and oxidative dehydrogenation of ethane as probe reactions, we demonstrate that selectively blocking low coordination metal sites by oxide overcoats can provide another strategy to enhance both the durability and selectivity of metal catalysts.

Original languageEnglish
Pages (from-to)1806-1815
Number of pages10
JournalAccounts of Chemical Research
Volume46
Issue number8
DOIs
Publication statusPublished - Aug 20 2013

Fingerprint

Atomic layer deposition
Stabilization
Metals
Catalysts
Oxides
Metal nanoparticles
Chemical analysis
Thickness control
Petroleum refining
Vehicle Emissions
Fischer-Tropsch synthesis
Ethane
Catalyst selectivity
Aluminum Oxide
Dehydrogenation
Temperature control
Impregnation
Methanol
Surface treatment
Chemical vapor deposition

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Synthesis and Stabilization of Supported Metal Catalysts by Atomic Layer Deposition. / Lu, Junling; Elam, Jeffrey W.; Stair, Peter C.

In: Accounts of Chemical Research, Vol. 46, No. 8, 20.08.2013, p. 1806-1815.

Research output: Contribution to journalArticle

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