Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)

Rachid Touzani; Michael Haibach; Agnieszka J. Nawara-Hultzsch; Sghir El Kadiri; Thomas J. Emge; Alan S Goldman

doi:10.1016/j.poly.2011.06.038

Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)

Rachid Touzani, Michael Haibach, Agnieszka J. Nawara-Hultzsch, Sghir El Kadiri, Thomas J. Emge, Alan S Goldman

Rutgers University

Research output: Contribution to journal › Article

9 Citations (Scopus)

Abstract

The complexation of the simple 1-hydroxymethyl-3,5-dimethylpyrazole (HL) ligand with Fe and Ni salts leads to interesting polynuclear complexes in good yield. X-ray diffraction reveals that the resulting complexes (μ₄-L)₄Ni₄Cl₄(H ₂O)₄ and (μ₂-L) ₄(μ₃-L)₂Fe₈Cl₁₆(μ ₄-O)₆ adopt cubane-type and open-cubane-type structures in the solid state.

Original language	English
Pages (from-to)	2530-2534
Number of pages	5
Journal	Polyhedron
Volume	30
Issue number	15
DOIs	https://doi.org/10.1016/j.poly.2011.06.038
Publication status	Published - Sep 21 2011

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cubane

Complexation

Salts

Ligands

X ray diffraction

synthesis

salts

solid state

ligands

diffraction

x rays

3,5-dimethylpyrazole

Keywords

Cubane and crystallography
Nitrogen-rich
Pyrazole ligand
Synthesis
X-ray

ASJC Scopus subject areas

Inorganic Chemistry
Materials Chemistry
Physical and Theoretical Chemistry

Cite this

Touzani, R., Haibach, M., Nawara-Hultzsch, A. J., El Kadiri, S., Emge, T. J., & Goldman, A. S. (2011). Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). Polyhedron, 30(15), 2530-2534. https://doi.org/10.1016/j.poly.2011.06.038

Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). / Touzani, Rachid; Haibach, Michael; Nawara-Hultzsch, Agnieszka J.; El Kadiri, Sghir; Emge, Thomas J.; Goldman, Alan S.

In: Polyhedron, Vol. 30, No. 15, 21.09.2011, p. 2530-2534.

Research output: Contribution to journal › Article

Touzani, R, Haibach, M, Nawara-Hultzsch, AJ, El Kadiri, S, Emge, TJ & Goldman, AS 2011, 'Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)', Polyhedron, vol. 30, no. 15, pp. 2530-2534. https://doi.org/10.1016/j.poly.2011.06.038

Touzani R, Haibach M, Nawara-Hultzsch AJ, El Kadiri S, Emge TJ, Goldman AS. Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). Polyhedron. 2011 Sep 21;30(15):2530-2534. https://doi.org/10.1016/j.poly.2011.06.038

Touzani, Rachid ; Haibach, Michael ; Nawara-Hultzsch, Agnieszka J. ; El Kadiri, Sghir ; Emge, Thomas J. ; Goldman, Alan S. / Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). In: Polyhedron. 2011 ; Vol. 30, No. 15. pp. 2530-2534.

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abstract = "The complexation of the simple 1-hydroxymethyl-3,5-dimethylpyrazole (HL) ligand with Fe and Ni salts leads to interesting polynuclear complexes in good yield. X-ray diffraction reveals that the resulting complexes (μ4-L)4Ni4Cl4(H 2O)4 and (μ2-L) 4(μ3-L)2Fe8Cl16(μ 4-O)6 adopt cubane-type and open-cubane-type structures in the solid state.",

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10.1016/j.poly.2011.06.038