Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II)

Rachid Touzani, Michael Haibach, Agnieszka J. Nawara-Hultzsch, Sghir El Kadiri, Thomas J. Emge, Alan S Goldman

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The complexation of the simple 1-hydroxymethyl-3,5-dimethylpyrazole (HL) ligand with Fe and Ni salts leads to interesting polynuclear complexes in good yield. X-ray diffraction reveals that the resulting complexes (μ4-L)4Ni4Cl4(H 2O)4 and (μ2-L) 43-L)2Fe8Cl164-O)6 adopt cubane-type and open-cubane-type structures in the solid state.

Original languageEnglish
Pages (from-to)2530-2534
Number of pages5
JournalPolyhedron
Volume30
Issue number15
DOIs
Publication statusPublished - Sep 21 2011

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cubane
Complexation
Salts
Ligands
X ray diffraction
synthesis
salts
solid state
ligands
diffraction
x rays
3,5-dimethylpyrazole

Keywords

  • Cubane and crystallography
  • Nitrogen-rich
  • Pyrazole ligand
  • Synthesis
  • X-ray

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Cite this

Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). / Touzani, Rachid; Haibach, Michael; Nawara-Hultzsch, Agnieszka J.; El Kadiri, Sghir; Emge, Thomas J.; Goldman, Alan S.

In: Polyhedron, Vol. 30, No. 15, 21.09.2011, p. 2530-2534.

Research output: Contribution to journalArticle

Touzani, Rachid ; Haibach, Michael ; Nawara-Hultzsch, Agnieszka J. ; El Kadiri, Sghir ; Emge, Thomas J. ; Goldman, Alan S. / Synthesis and structural characterization of new polynuclear complexes of 1-hydroxymethyl-3,5-dimethylpyrazole with Ni(II) and Fe(II). In: Polyhedron. 2011 ; Vol. 30, No. 15. pp. 2530-2534.
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AU - Goldman, Alan S

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