Abstract
The complexation of the simple 1-hydroxymethyl-3,5-dimethylpyrazole (HL) ligand with Fe and Ni salts leads to interesting polynuclear complexes in good yield. X-ray diffraction reveals that the resulting complexes (μ4-L)4Ni4Cl4(H 2O)4 and (μ2-L) 4(μ3-L)2Fe8Cl16(μ 4-O)6 adopt cubane-type and open-cubane-type structures in the solid state.
Original language | English |
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Pages (from-to) | 2530-2534 |
Number of pages | 5 |
Journal | Polyhedron |
Volume | 30 |
Issue number | 15 |
DOIs | |
Publication status | Published - Sep 21 2011 |
Keywords
- Cubane and crystallography
- Nitrogen-rich
- Pyrazole ligand
- Synthesis
- X-ray
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
- Materials Chemistry