Abstract
The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).
| Original language | English |
|---|---|
| Pages (from-to) | 2135-2137 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 5 |
| Publication status | Published - May 1994 |
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
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Wang, K., Emge, T. J., & Goldman, A. S. (1994). Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide. Organometallics, 13(5), 2135-2137.