Synthesis and Structure of a (Diphosphoxane)rhodium(I) Complex. Novel Reaction with CO To Liberate a Phosphinidene Oxide

Kun Wang; Thomas J. Emge; Alan S. Goldman

doi:10.1021/om00017a088

Synthesis and Structure of a (Diphosphoxane)rhodium(I) Complex. Novel Reaction with CO To Liberate a Phosphinidene Oxide

Kun Wang, Thomas J. Emge, Alan S. Goldman

Rutgers University

Research output: Contribution to journal › Article › peer-review

18 Citations (Scopus)

Abstract

The synthesis and crystal and molecular structure of RhCl[η²-(Me₂N)₂POP(NMe₂)₂-P,P′] [P-(NMe₂)₃] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe₂)₃]₂(CO)Cl (3).

Original language	English
Pages (from-to)	2135-2137
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	5
DOIs	https://doi.org/10.1021/om00017a088
Publication status	Published - May 1 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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abstract = "The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P-(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe2)3]2(CO)Cl (3).",

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AB - The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P-(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe2)3]2(CO)Cl (3).

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