Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide

K. Wang, T. J. Emge, Alan S Goldman

Research output: Contribution to journalArticle

17 Citations (Scopus)

Abstract

The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).

Original languageEnglish
Pages (from-to)2135-2137
Number of pages3
JournalOrganometallics
Volume13
Issue number5
Publication statusPublished - May 1994

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Rhodium
Carbon Monoxide
rhodium
Oxides
molecular structure
ligands
crystal structure
oxides
synthesis
Molecular structure
Crystal structure
Ligands

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Organic Chemistry

Cite this

Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide. / Wang, K.; Emge, T. J.; Goldman, Alan S.

In: Organometallics, Vol. 13, No. 5, 05.1994, p. 2135-2137.

Research output: Contribution to journalArticle

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