Abstract
The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P-(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe2)3]2(CO)Cl (3).
Original language | English |
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Pages (from-to) | 2135-2137 |
Number of pages | 3 |
Journal | Organometallics |
Volume | 13 |
Issue number | 5 |
DOIs | |
Publication status | Published - May 1 1994 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry