Abstract
The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).
| Original language | English |
|---|---|
| Pages (from-to) | 2135-2137 |
| Number of pages | 3 |
| Journal | Organometallics |
| Volume | 13 |
| Issue number | 5 |
| Publication status | Published - May 1994 |
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ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry
Cite this
Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide. / Wang, K.; Emge, T. J.; Goldman, Alan S.
In: Organometallics, Vol. 13, No. 5, 05.1994, p. 2135-2137.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Synthesis and structure of a (diphosphoxane)rhodium(I) complex. Novel reaction with CO to liberate phosphinidene oxide
AU - Wang, K.
AU - Emge, T. J.
AU - Goldman, Alan S
PY - 1994/5
Y1 - 1994/5
N2 - The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).
AB - The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).
UR - http://www.scopus.com/inward/record.url?scp=0028442011&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=0028442011&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0028442011
VL - 13
SP - 2135
EP - 2137
JO - Organometallics
JF - Organometallics
SN - 0276-7333
IS - 5
ER -