The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh[P(NMe2)3]2(CO)Cl (3).
|Number of pages||3|
|Publication status||Published - May 1994|
ASJC Scopus subject areas
- Inorganic Chemistry
- Organic Chemistry