The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P-(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe2)3]2(CO)Cl (3).
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Organic Chemistry
- Inorganic Chemistry