Synthesis and Structure of a (Diphosphoxane)rhodium(I) Complex. Novel Reaction with CO To Liberate a Phosphinidene Oxide

Kun Wang, Thomas J. Emge, Alan S. Goldman

Research output: Contribution to journalArticlepeer-review

18 Citations (Scopus)

Abstract

The synthesis and crystal and molecular structure of RhCl[η2-(Me2N)2POP(NMe2)2-P,P′] [P-(NMe2)3] (1) are reported. 1 undergoes a novel reaction with CO in which the diphosphoxane ligand is cleaved, yielding (dimethylamino)phosphinidene oxide and Rh-[P(NMe2)3]2(CO)Cl (3).

Original languageEnglish
Pages (from-to)2135-2137
Number of pages3
JournalOrganometallics
Volume13
Issue number5
DOIs
Publication statusPublished - May 1 1994

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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