TY - JOUR
T1 - Synthesis and Structure of the Cluster [NaAu12Se8]3−
T2 - An Inorganic Cryptand Complex
AU - Huang, Song‐Ping ‐P
AU - Kanatzidis, Mercouri G.
PY - 1992/6
Y1 - 1992/6
N2 - A cube with twelve linearly coordinated gold atoms in the middle of the edges and eight trigonally coordinated selenium atoms at the corners is found in the structure of the title compound 1 (see right). A sodium ion is encapsulated in the center of the cube and interacts with the gold atoms. The (Et4N) 3 salt of this inorganic cryptand complex is formed in the reaction of AuCN and Na2Se in the presence of Et4NCl. (Figure Presented.)
AB - A cube with twelve linearly coordinated gold atoms in the middle of the edges and eight trigonally coordinated selenium atoms at the corners is found in the structure of the title compound 1 (see right). A sodium ion is encapsulated in the center of the cube and interacts with the gold atoms. The (Et4N) 3 salt of this inorganic cryptand complex is formed in the reaction of AuCN and Na2Se in the presence of Et4NCl. (Figure Presented.)
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U2 - 10.1002/anie.199207871
DO - 10.1002/anie.199207871
M3 - Article
AN - SCOPUS:33748245032
VL - 31
SP - 787
EP - 789
JO - Angewandte Chemie - International Edition
JF - Angewandte Chemie - International Edition
SN - 1433-7851
IS - 6
ER -