Synthesis, characterization and crystal structure of a new thermally stable and volatile precursor [bis(1,1,1,2,2,3,3,7,7,8,8,9,9,9-tetradecafluorononane- 4,6-dionato)2-tetraglyme]barium(II) for MOCVD application

Graziella Malandrino, Ignazio L. Fragalà, Deborah A. Neumayer, Charlotte L. Stern, Bruce J. Hinds, Tobin J Marks

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

The new tetraglyme adduct of barium bis(1,1,1,2,2,3,3,7,7,8,8,9,9,9- tetradecafluorononane-4,6-dionate) complex has been prepared and characterized by X-ray crystallography, 1H and 13C NMR, IR, mass spectrometry and thermogravimetric-differential scanning calorimetric (TG-DSC) analyses. The complex can be easily and cleanly vaporized at 90°C (10 -2 mmHg) from the liquid phase. It is thermally stable, volatile and non-hygroscopic. The thermal stability can be attributed to the saturation of coordination sites due to the tetraglyme ligand which appears wrapped around the barium centre. The adduct has been used as an MOCVD precursor for the synthesis of BaPbO3 films by a combined approach of MOCVD and lead vapour diffusion. PbCO3 has been used as lead source.

Original languageEnglish
Pages (from-to)1061-1066
Number of pages6
JournalJournal of Materials Chemistry
Volume4
Issue number7
Publication statusPublished - 1994

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Metallorganic chemical vapor deposition
Barium
adducts
barium
metalorganic chemical vapor deposition
Lead
Crystal structure
crystal structure
X ray crystallography
synthesis
crystallography
Mass spectrometry
liquid phases
Thermodynamic stability
thermal stability
mass spectroscopy
Vapors
Ligands
Nuclear magnetic resonance
vapors

ASJC Scopus subject areas

  • Materials Science(all)
  • Materials Chemistry
  • Physical and Theoretical Chemistry

Cite this

Synthesis, characterization and crystal structure of a new thermally stable and volatile precursor [bis(1,1,1,2,2,3,3,7,7,8,8,9,9,9-tetradecafluorononane- 4,6-dionato)2-tetraglyme]barium(II) for MOCVD application. / Malandrino, Graziella; Fragalà, Ignazio L.; Neumayer, Deborah A.; Stern, Charlotte L.; Hinds, Bruce J.; Marks, Tobin J.

In: Journal of Materials Chemistry, Vol. 4, No. 7, 1994, p. 1061-1066.

Research output: Contribution to journalArticle

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abstract = "The new tetraglyme adduct of barium bis(1,1,1,2,2,3,3,7,7,8,8,9,9,9- tetradecafluorononane-4,6-dionate) complex has been prepared and characterized by X-ray crystallography, 1H and 13C NMR, IR, mass spectrometry and thermogravimetric-differential scanning calorimetric (TG-DSC) analyses. The complex can be easily and cleanly vaporized at 90°C (10 -2 mmHg) from the liquid phase. It is thermally stable, volatile and non-hygroscopic. The thermal stability can be attributed to the saturation of coordination sites due to the tetraglyme ligand which appears wrapped around the barium centre. The adduct has been used as an MOCVD precursor for the synthesis of BaPbO3 films by a combined approach of MOCVD and lead vapour diffusion. PbCO3 has been used as lead source.",
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AU - Hinds, Bruce J.

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