Synthesis, characterization and crystal structure of (cis-P,P′-diphenyl-1,4-diphospha-cyclohexane)molybdenum(0)tetracarbonyl

Gerard M. Carroll, Susie M. Miller, Monte Helm

Research output: Contribution to journalArticle

Abstract

The preparation of the novel (cis-P,P′-diphenyl-1,4-diphospha-cyclohexane)molybdenum(0)tetracarbonyl complex is described. The spectral data and X-ray structure of the title complex are reported. The results of the crystallographic work show a distorted octahedral complex around the metal center, the first of its kind reported for the P,P′-diphenyl-1,4-diphospha-cyclohexane ligand.

Original languageEnglish
Pages (from-to)534-536
Number of pages3
JournalInorganic Chemistry Communications
Volume13
Issue number4
DOIs
Publication statusPublished - Apr 2010

Fingerprint

Molybdenum
Cyclohexane
cyclohexane
molybdenum
Crystal structure
crystal structure
Coordination Complexes
synthesis
Ligands
X rays
preparation
ligands
Metals
metals
x rays
diphenyl

Keywords

  • Bidentate phosphine ligands
  • Molybdenum tetracarbonyl complexes
  • P,P′-diphenyl-1,4-diphospha-cyclohexane
  • Phosphine ligands

ASJC Scopus subject areas

  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Materials Chemistry

Cite this

Synthesis, characterization and crystal structure of (cis-P,P′-diphenyl-1,4-diphospha-cyclohexane)molybdenum(0)tetracarbonyl. / Carroll, Gerard M.; Miller, Susie M.; Helm, Monte.

In: Inorganic Chemistry Communications, Vol. 13, No. 4, 04.2010, p. 534-536.

Research output: Contribution to journalArticle

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