Synthesis, characterization, and marked polymerization selectivity characteristics of binuclear phenoxyiminato organozirconium catalysts

Michael R. Salata, Tobin J. Marks

Research output: Contribution to journalArticle

92 Citations (Scopus)

Abstract

The new binuclear phenoxyiminato zirconium complex {1,7-(O)2C10H4-2,7-[CH=N(2,6-iPr2C6H3)]2}Zr2Cl6(THF)2 (FI2-Zr2) polymerizes ethylene with greater activity (8×) than the mononuclear analogue. Also, this catalyst produces high molecular weight ethylene + 1-hexene copolymers, while the mononuclear analogue yields only traces of copolymer under identical conditions. This ability to produce copolymers suggests cooperativity between the two Zr centers which promotes 1-hexene co-enchainment.

Original languageEnglish
Pages (from-to)12-13
Number of pages2
JournalJournal of the American Chemical Society
Volume130
Issue number1
DOIs
Publication statusPublished - Jan 9 2008

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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