Synthesis, characterization, and solution properties of skeletally stabilized triphosphazanes

Monte Helm, Stephanie A. Katz, Tomasz W. Imiolczyk, Robert M. Hands, Arlan D. Norman

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Abstract

The new skeletally stabilized dichlorotriphosphazanes C6H4N2(PhPCl)2PPh (5) and C6H4N2(MePCl)2PMe (6) have been prepared from reactions between PhPCl2 or MePCl2 and 1,2-(NH2)2C6H4 or 1,2-(Me3SiNH)2C6H4, respectively. Reaction of PhPCl2 with the phosphadiazole C2H4(Me3SiN)2PPh yields triphosphazane C2H4N2(PhPCl)2PPh (8).

Original languageEnglish
Pages (from-to)3167-3172
Number of pages6
JournalInorganic Chemistry
Volume38
Issue number13
Publication statusPublished - 1999

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ASJC Scopus subject areas

  • Inorganic Chemistry

Cite this

Helm, M., Katz, S. A., Imiolczyk, T. W., Hands, R. M., & Norman, A. D. (1999). Synthesis, characterization, and solution properties of skeletally stabilized triphosphazanes. Inorganic Chemistry, 38(13), 3167-3172.

Synthesis, characterization, and solution properties of skeletally stabilized triphosphazanes. / Helm, Monte; Katz, Stephanie A.; Imiolczyk, Tomasz W.; Hands, Robert M.; Norman, Arlan D.

In: Inorganic Chemistry, Vol. 38, No. 13, 1999, p. 3167-3172.

Research output: Contribution to journalArticle

Helm, M, Katz, SA, Imiolczyk, TW, Hands, RM & Norman, AD 1999, 'Synthesis, characterization, and solution properties of skeletally stabilized triphosphazanes', Inorganic Chemistry, vol. 38, no. 13, pp. 3167-3172.
Helm, Monte ; Katz, Stephanie A. ; Imiolczyk, Tomasz W. ; Hands, Robert M. ; Norman, Arlan D. / Synthesis, characterization, and solution properties of skeletally stabilized triphosphazanes. In: Inorganic Chemistry. 1999 ; Vol. 38, No. 13. pp. 3167-3172.
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