The new skeletally stabilized dichlorotriphosphazanes C6H4N2(PhPCl)2PPh (5) and C6H4N2(MePCl)2PMe (6) have been prepared from reactions between PhPCl2 or MePCl2 and 1,2-(NH2)2C6H4 or 1,2-(Me3SiNH)2C6H4, respectively. Reaction of PhPCl2 with the phosphadiazole C2H4(Me3SiN)2PPh yields triphosphazane C2H4N2(PhPCl)2PPh (8).
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry