Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14

Shilie Pan, Jared P. Smit, Michael R. Marvel, Evan S. Stampler, Jacob M. Haag, Jaewook Baek, P. Shiv Halasyamani, Kenneth R Poeppelmeier

Research output: Contribution to journalArticle

31 Citations (Scopus)

Abstract

Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

Original languageEnglish
Pages (from-to)2087-2091
Number of pages5
JournalJournal of Solid State Chemistry
Volume181
Issue number8
DOIs
Publication statusPublished - Aug 2008

Fingerprint

Harmonic generation
Optical properties
Crystal structure
Radiation
optical properties
crystal structure
synthesis
polyhedrons
harmonic generations
radiation
cells

Keywords

  • Crystal growth
  • Crystal structure
  • Nonlinear optical properties
  • Oxide

ASJC Scopus subject areas

  • Condensed Matter Physics
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Ceramics and Composites
  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry

Cite this

Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14. / Pan, Shilie; Smit, Jared P.; Marvel, Michael R.; Stampler, Evan S.; Haag, Jacob M.; Baek, Jaewook; Halasyamani, P. Shiv; Poeppelmeier, Kenneth R.

In: Journal of Solid State Chemistry, Vol. 181, No. 8, 08.2008, p. 2087-2091.

Research output: Contribution to journalArticle

Pan, S, Smit, JP, Marvel, MR, Stampler, ES, Haag, JM, Baek, J, Halasyamani, PS & Poeppelmeier, KR 2008, 'Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14', Journal of Solid State Chemistry, vol. 181, no. 8, pp. 2087-2091. https://doi.org/10.1016/j.jssc.2008.05.008
Pan, Shilie ; Smit, Jared P. ; Marvel, Michael R. ; Stampler, Evan S. ; Haag, Jacob M. ; Baek, Jaewook ; Halasyamani, P. Shiv ; Poeppelmeier, Kenneth R. / Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14. In: Journal of Solid State Chemistry. 2008 ; Vol. 181, No. 8. pp. 2087-2091.
@article{cc018a2cbd1d40a69b7f8b034138561c,
title = "Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14",
abstract = "Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) {\AA}, b=9.3917(11) {\AA}, c=3.4566(4) {\AA}, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.",
keywords = "Crystal growth, Crystal structure, Nonlinear optical properties, Oxide",
author = "Shilie Pan and Smit, {Jared P.} and Marvel, {Michael R.} and Stampler, {Evan S.} and Haag, {Jacob M.} and Jaewook Baek and Halasyamani, {P. Shiv} and Poeppelmeier, {Kenneth R}",
year = "2008",
month = "8",
doi = "10.1016/j.jssc.2008.05.008",
language = "English",
volume = "181",
pages = "2087--2091",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Academic Press Inc.",
number = "8",

}

TY - JOUR

T1 - Synthesis, crystal structure, and nonlinear optical properties of Bi2Cu5B4O14

AU - Pan, Shilie

AU - Smit, Jared P.

AU - Marvel, Michael R.

AU - Stampler, Evan S.

AU - Haag, Jacob M.

AU - Baek, Jaewook

AU - Halasyamani, P. Shiv

AU - Poeppelmeier, Kenneth R

PY - 2008/8

Y1 - 2008/8

N2 - Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

AB - Bi2Cu5B4O14 crystallizes in the noncentrosymmetric triclinic space group P1 (No. 1) with cell parameters a=10.1381(11) Å, b=9.3917(11) Å, c=3.4566(4) Å, α=105.570(2)°, β=92.275(2)°, γ=107.783(2)°, Z=1 and R1=0.0401 and wR2=0.0980. It is a layered structure that is built up from sheets of rectangular CuO4 and trigonal BO3 groups. The sheets are connected by infinite chains of edge shared BiO6 polyhedra that intersect the bc plane at an angle slightly greater than 90°. The second-harmonic generation efficiency of Bi2Cu5B4O14, using 1064 nm radiation, is about one half times that of KH2PO4.

KW - Crystal growth

KW - Crystal structure

KW - Nonlinear optical properties

KW - Oxide

UR - http://www.scopus.com/inward/record.url?scp=52649176425&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=52649176425&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2008.05.008

DO - 10.1016/j.jssc.2008.05.008

M3 - Article

AN - SCOPUS:52649176425

VL - 181

SP - 2087

EP - 2091

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

IS - 8

ER -